Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

The story of C− C bond formation includes several reactions, and surely Suzuki‐Miyaura is
among the most outstanding ones. Herein, a brief historical overview of insights regarding …

Monitoring reactive intermediates can provide vital information in the study of synthetic
reaction mechanisms, enabling the design of new catalysts and methods. Many synthetic …

Synthetic organic chemistry experienced a significant advance in the last quarter of the 20th
century with the advent of the transition-metal catalyzed cross-coupling reactions. The utility …

The scarcity of complex intermediates in pharmaceutical research motivates the pursuit of
reaction optimization protocols on submilligram scales. We report here the development of …

Suzuki–Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal
catalysed carbon–carbon bond forming reaction to date. Its success originates from a …

The mechanism of phenoxyimine (FI)− cobalt-catalyzed C (sp2)–C (sp3) Suzuki–Miyaura
cross-coupling was studied using a combination of kinetic measurements and catalytic and …

Abstract The Suzuki–Miyaura cross-coupling of organoboron nucleophiles with aryl halide
electrophiles is one of the most widely used carbon–carbon bond-forming reactions in …

Despite the widespread application of Suzuki-Miyaura cross-coupling to forge carbon-
carbon bonds, the structure of the reactive intermediates underlying the key transmetalation …

Synthesis of free‐standing two‐dimensional (2D) conjugated covalent organic framework
(COF) films linked by C− C bonds is highly desirable. Now a very simple and mild strategy …