Tailoring the photoluminescence of atomically precise nanoclusters

X Kang, M Zhu - Chemical Society Reviews, 2019 - pubs.rsc.org
Due to their atomically precise structures and intriguing chemical/physical properties, metal
nanoclusters are an emerging class of modular nanomaterials. Photo-luminescence (PL) is …

Super atomic clusters: design rules and potential for building blocks of materials

P Jena, Q Sun - Chemical reviews, 2018 - ACS Publications
Atomic clusters, consisting of a few to a few thousand atoms, have emerged over the past 40
years as the ultimate nanoparticles, whose structure and properties can be controlled one …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Recent progress in functional atom-precise coinage metal clusters protected by alkynyl ligands

MM Zhang, XY Dong, YJ Wang, SQ Zang… - Coordination Chemistry …, 2022 - Elsevier
The selection of surface organic ligands is very important for the preparation of coinage
metal clusters with precise structures, which can dictate the related properties of metal …

Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters

RR Nasaruddin, T Chen, N Yan, J Xie - Coordination Chemistry Reviews, 2018 - Elsevier
Abstract Ultrasmall (< 2 nm) ligand-protected metal nanoclusters (NCs) have been an
emerging class of functional materials with rich coordination chemistry, finding increasing …

Metal nanoclusters stabilized by selenol ligands

X Kang, M Zhu - Small, 2019 - Wiley Online Library
The past decades have witnessed great advances in controllable synthesis, structure
determination, and property investigation of metal nanoclusters. Selenolated nanoclusters, a …

Significantly enhanced electrocatalytic activity of Au25 clusters by single platinum atom doping

Y Lu, C Zhang, X Li, AR Frojd, W Xing, AZ Clayborne… - Nano Energy, 2018 - Elsevier
The search for highly active catalysts with low-Pt content to advance the commercialization
of fuel cells is continuing to receive ample attention. Herein, we report that by doping a …

Understanding and designing the gold–bio interface: Insights from simulations

P Charchar, AJ Christofferson, N Todorova, I Yarovsky - Small, 2016 - Wiley Online Library
Gold nanoparticles (AuNPs) are an integral part of many exciting and novel biomedical
applications, sparking the urgent need for a thorough understanding of the physicochemical …

Ligand Exchange Reactions in Thiolate-Protected Au25 Nanoclusters with Selenolates or Tellurolates: Preferential Exchange Sites and Effects on Electronic …

S Hossain, W Kurashige, S Wakayama… - The Journal of …, 2016 - ACS Publications
Ligand exchange reactions can introduce new ligands onto clusters to afford new
physical/chemical properties and functions. Many studies on the ligand exchange reactions …

Understanding and Practical Use of Ligand and Metal Exchange Reactions in Thiolate‐Protected Metal Clusters to Synthesize Controlled Metal Clusters

Y Niihori, S Hossain, S Sharma, B Kumar… - The Chemical …, 2017 - Wiley Online Library
It is now possible to accurately synthesize thiolate (SR)‐protected gold clusters (Aun (SR) m)
with various chemical compositions with atomic precision. The geometric structure …