Investigating zirconium alloy corrosion with advanced experimental techniques: A review

E Kautz, B Gwalani, Z Yu, T Varga, K Geelhood… - Journal of Nuclear …, 2023 - Elsevier
Zirconium-based alloys (Zr alloys) are key materials in the nuclear industry due to their
thermal stability, mechanical durability, and low thermal neutron cross section. However …

Testing the Cabrera–Mott oxidation model for aluminum under realistic conditions with near-ambient pressure photoemission

LP Ramírez, F Bournel, JJ Gallet, L Dudy… - The Journal of …, 2022 - ACS Publications
Using the nascent band theory of solids, Cabrera and Mott designed in the late 1940s a
model for the low-temperature oxidation of metals that still stands today as a landmark. The …

Atomic-scale characterization of (electro-) catalysts and battery materials by atom probe tomography

T Li, A Devaraj, N Kruse - Cell Reports Physical Science, 2022 - cell.com
To optimize the performance of heterogeneous (electro-) catalysts and battery electrodes, it
is essential to establish the structure-property relationships. This can only be achieved by …

Visualizing the nanoscale oxygen and cation transport mechanisms during the early stages of oxidation of Fe–Cr–Ni alloy using in situ atom probe tomography

A Devaraj, DJ Barton, CH Li… - Advanced Materials …, 2022 - Wiley Online Library
Understanding the early stages of interactions between oxygen and material surfaces—
especially at very high spatial resolutions—is highly beneficial for fields ranging from …

Nanoscale perspectives of metal degradation via in situ atom probe tomography

SV Lambeets, EJ Kautz, MG Wirth, GJ Orren… - Topics in …, 2020 - Springer
We report a unique in situ instrument development effort dedicated to studying gas/solid
interactions relevant to heterogeneous catalysis and early stages of oxidation of materials …

Rapid assessment of structural and compositional changes during early stages of zirconium alloy oxidation

EJ Kautz, B Gwalani, SVM Lambeets, L Kovarik… - npj Materials …, 2020 - nature.com
A multimodal chemical imaging approach has been developed and applied to detail the
dynamic, atomic-scale changes associated with oxidation of a zirconium alloy (Zircaloy-4) …

Emergence of subsurface oxygen on Rh (111)

ME Turano, EA Jamka, MZ Gillum… - The Journal of …, 2021 - ACS Publications
Oxygen atoms on transition metal surfaces are highly mobile under the demanding
pressures and temperatures typically employed for heterogeneously catalyzed oxidation …

Surface microscopy of atomic and molecular hydrogen from field-evaporating semiconductors

L Rigutti, E Di Russo, F Chabanais, I Blum… - The Journal of …, 2021 - ACS Publications
We report on the microscopic behavior of residual hydrogen on nanometric field emitters. By
using homogeneous or heterostructured semiconductor specimens analyzed in a laser …

Mechanistic insights into selective oxidation and corrosion of multi-principal element alloys from high resolution and in situ microscopy

EJ Kautz, DK Schreiber, A Devaraj, B Gwalani - Materialia, 2021 - Elsevier
Multiple principal element alloys (MPEAs) have drawn significant recent interest from the
metallurgical research community. These novel alloys have the potential to replace …

Oxygen adsorption, subsurface oxygen layer formation and reaction with hydrogen on surfaces of a Pt–Rh alloy nanocrystal

S Owczarek, SV Lambeets, R Bryl, C Barroo… - Topics in …, 2020 - Springer
The oxygen adsorption and its catalytic reaction with hydrogen on Pt–Rh single crystals
were studied at the nanoscale by Field Emission Microscopy (FEM) and Field Ion …