C–H⋯ S hydrogen bonding interactions
The short C–H⋯ S contacts found in available structural data for both small molecules and
larger biomolecular systems suggest that such contacts are an often overlooked yet …
larger biomolecular systems suggest that such contacts are an often overlooked yet …
Structural and Redox Interconversions of Sulfur Ligands of Transition Metal Complexes
The interactions between transition metals and sulfur have long been studied for potential
applications in catalysis and energy storage and due to the relevance of these motifs in …
applications in catalysis and energy storage and due to the relevance of these motifs in …
Partial synthetic models of FeMoco with sulfide and carbyne ligands: Effect of interstitial atom in nitrogenase active site
Nitrogen-fixing organisms perform dinitrogen reduction to ammonia at an Fe-M (M= Mo, Fe,
or V) cofactor (FeMco) of nitrogenase. FeMco displays eight metal centers bridged by …
or V) cofactor (FeMco) of nitrogenase. FeMco displays eight metal centers bridged by …
Thionitrite (SNO−) and Perthionitrite (SSNO−) are Simple Synthons for Nitrosylated Iron Sulfur Clusters
S/N crosstalk species derived from the interconnected reactivity of H2S and NO facilitate the
transport of reactive sulfur and nitrogen species in signaling, transport, and regulatory …
transport of reactive sulfur and nitrogen species in signaling, transport, and regulatory …
Chemoselective Proteomics, Zinc Fingers, and a Zinc(II) Model for H2S Mediated Persulfidation
The gasotransmitter hydrogen sulfide (H2S) is thought to be involved in the post‐
translational modification of cysteine residues to produce reactive persulfides. A persulfide …
translational modification of cysteine residues to produce reactive persulfides. A persulfide …
Unveiling the underappreciated: The bonding features of C–H⋯ S–S interactions observed from rotational spectroscopy
W Lv, Y Xu, T Yang, L Wang, J Huang… - The Journal of …, 2024 - pubs.aip.org
The C–H⋯ S–S interactions are fundamentally important to understand the stability of
biomacromolecules and their binding with small molecules, but they are still …
biomacromolecules and their binding with small molecules, but they are still …
Bioinorganic chemistry of hydrogen sulfide: detection, delivery, and interactions with metalloproteins
Hydrogen sulfide (H2S) has received significant attention in the past two decades for its role
in biological processes. Despite numerous studies on the biological activity of this gas, the …
in biological processes. Despite numerous studies on the biological activity of this gas, the …
Reactions of a Dioxidomolybdenum (VI) Complex with Thionation Reagents—Formation of Mo (IV) Species with Sulfur Donors
E Salojärvi, A Peuronen, N Sapkota, A Lehtonen - Molecules, 2022 - mdpi.com
Molecular molybdenum complexes with sulfur donor ligands are generally studied as
soluble model compounds for molybdenum enzymes essential for life. The …
soluble model compounds for molybdenum enzymes essential for life. The …
Synthesis of Terminal Bis (hydrosulfido) and Disulfido Complexes of Ni (II) from a Geometrically Frustrated Tetrahedral Ni (II) Chloride Complex
TJ Sherbow, L Zakharov, MD Pluth - Inorganic Chemistry, 2021 - ACS Publications
Recent studies have highlighted how reactive sulfur species (RSS) can be regulated and
transported by metal–sulfur coordination compounds. We report herein the reactivity of PhB …
transported by metal–sulfur coordination compounds. We report herein the reactivity of PhB …
Reactivity between late first-row transition metal halides and the ligand bis (2-pyridylmethyl) disulfide: Vibrantly-colored compounds with variable molecular …
N Cena, RL Blanski, MA Coppola, AN Giordano… - Inorganica Chimica …, 2022 - Elsevier
The reactivity between late first-row transition metal halides and the disulfide-containing
ligand bis (2-pyridylmethyl) disulfide was examined. From this survey, a series of …
ligand bis (2-pyridylmethyl) disulfide was examined. From this survey, a series of …