Structure, function, self-assembly, and applications of bottlebrush copolymers
R Verduzco, X Li, SL Pesek, GE Stein - Chemical Society Reviews, 2015 - pubs.rsc.org
Bottlebrush polymers are a type of branched or graft polymer with polymeric side-chains
attached to a linear backbone, and the unusual architectures of bottlebrushes provide a …
attached to a linear backbone, and the unusual architectures of bottlebrushes provide a …
[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …
Expanding the scope of RAFT polymerization: recent advances and new horizons
Reversible deactivation radical polymerization (RDRP) has revolutionized modern polymer
chemistry over the past two decades, thus laying the groundwork for the synthesis of …
chemistry over the past two decades, thus laying the groundwork for the synthesis of …
RAFT polymerization to form stimuli-responsive polymers
G Moad - Polymer Chemistry, 2017 - pubs.rsc.org
Stimuli-responsive polymers adapt to their surrounding environment. These polymers are
capable of responding to a variety of external stimuli, which include optical, electrical …
capable of responding to a variety of external stimuli, which include optical, electrical …
Living radical polymerization by the RAFT process–a third update
This paper provides a third update to the review of reversible deactivation radical
polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC (= S) SR) by a …
polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC (= S) SR) by a …
Architectural code for rubber elasticity: from supersoft to superfirm materials
SS Sheiko, AV Dobrynin - Macromolecules, 2019 - ACS Publications
The current approach to regulating mechanical properties of elastomeric materials is
predominately based on the exploratory mixing of different polymers, solvents, and fillers …
predominately based on the exploratory mixing of different polymers, solvents, and fillers …
Molecular structure of bottlebrush polymers in melts
Bottlebrushes are fascinating macromolecules that display an intriguing combination of
molecular and particulate features having vital implications in both living and synthetic …
molecular and particulate features having vital implications in both living and synthetic …
Molecular bottlebrushes: new opportunities in nanomaterials fabrication
J Rzayev - 2012 - ACS Publications
This Viewpoint highlights the ability of molecular bottlebrushes to serve as highly tunable
building blocks for creating nanostructured materials via molecular templating, solution …
building blocks for creating nanostructured materials via molecular templating, solution …
Aqueous self-assembly of giant bottlebrush block copolymer surfactants as shape-tunable building blocks
Programmed self-assembly of well-defined molecular building blocks enables the
fabrication of precisely structured nanomaterials. In this work, we explore a new class of …
fabrication of precisely structured nanomaterials. In this work, we explore a new class of …
Materials design of highly branched bottlebrush polymers at the intersection of modeling, synthesis, processing, and characterization
Highly branched “bottlebrush” polymers are a class of macromolecules characterized by
side chains that are densely grafted from a backbone that is typically linear. Their unique …
side chains that are densely grafted from a backbone that is typically linear. Their unique …