Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Activated ester containing polymers: opportunities and challenges for the design of functional macromolecules

A Das, P Theato - Chemical reviews, 2016 - ACS Publications
Rapidly growing demand of functional polymers in various interdisciplinary areas of
research has accentuated the need for modern synthetic tools to develop advanced …

Preparation of biomolecule-polymer conjugates by grafting-from using ATRP, RAFT, or ROMP

MS Messina, KMM Messina, A Bhattacharya… - Progress in polymer …, 2020 - Elsevier
Biomolecule-polymer conjugates are constructs that take advantage of the functional or
otherwise beneficial traits inherent to biomolecules and combine them with synthetic …

Bioapplications of RAFT polymerization

C Boyer, V Bulmus, TP Davis, V Ladmiral, J Liu… - Chemical …, 2009 - ACS Publications
A living radical polymerization (LRP) is a free radical polymerization that aims at displaying
living character,(ie, does not terminate or transfer and is able to continue polymerization …

Transition metal-catalyzed living radical polymerization: toward perfection in catalysis and precision polymer synthesis

M Ouchi, T Terashima, M Sawamoto - Chemical Reviews, 2009 - ACS Publications
Precision control of radical polymerization, or living radical polymerization, has been among
the most important and long-waited subjects in polymer chemistry and macromolecular …

Nanostructured functional materials prepared by atom transfer radical polymerization

K Matyjaszewski, NV Tsarevsky - Nature chemistry, 2009 - nature.com
Atom transfer radical polymerization (ATRP) is the most extensively studied controlled/living
radical polymerization (CRP) method, with the interest originating primarily in its simplicity …

Macromolecular engineering through click chemistry and other efficient transformations

BS Sumerlin, AP Vogt - Macromolecules, 2010 - ACS Publications
Precision synthesis of advanced polymeric materials requires efficient, robust, and facile
chemical reactions. Paradoxically, the synthesis of increasingly intricate macromolecular …

Modern trends in polymer bioconjugates design

JF Lutz, HG Börner - Progress in Polymer Science, 2008 - Elsevier
This review describes recent changes and progress in the field of polymer bioconjugation (ie
covalent attachment of synthetic polymers to biological entities such as nucleic acids …

Temperature-regulated activity of responsive polymer− protein conjugates prepared by grafting-from via RAFT polymerization

P De, M Li, SR Gondi, BS Sumerlin - Journal of the American …, 2008 - ACS Publications
A facile route to well-defined “smart” polymer− protein conjugates with tunable bioactivity is
reported. Protein modification with a reversible addition− fragmentation chain transfer …