Design of single chain magnets through cyanide-bearing six-coordinate complexes

R Lescouëzec, LM Toma, J Vaissermann… - Coordination chemistry …, 2005 - Elsevier
The design and preparation of stable cyanide-bearing six-coordinate complexes of formula
[MIII (L)(CN) x](x+ l− m)−(M= trivalent transition metal ion and L= polydentate blocking …

Dicyanometalate chemistry: A type of versatile building block for the construction of cyanide-bridged molecular architectures

S Wang, XH Ding, YH Li, W Huang - Coordination Chemistry Reviews, 2012 - Elsevier
Cyanide-bridged molecule-based magnetic materials with reduced dimensionality, such as
single-molecule magnets (SMMs) and single-chain magnets (SCMs), have attracted great …

Cyanide‐Bridged Iron(III)–Cobalt(II) Double Zigzag Ferromagnetic Chains: Two New Molecular Magnetic Nanowires

R Lescouëzec, J Vaissermann… - Angewandte Chemie …, 2003 - Wiley Online Library
The occurrence of a slow relaxation of the magnetization in a one-dimensional (1D) system
was recently reported by one of us.[1] The system was claimed to illustrate, for the first time …

[Fe(bpym)(CN)4]-: A New Building Block for Designing Single-Chain Magnets

LM Toma, R Lescouëzec, J Pasán… - Journal of the …, 2006 - ACS Publications
We herein present the preparation, crystal structure, magnetic properties, and theoretical
study of new heterobimetallic chains of formula {[FeIII (bpym)(CN4)] 2MII (H2O) 2}⊙ 6H2O …

Engineering of octacyanometalate-based coordination networks towards functionality

B Sieklucka, R Podgajny, P Przychodzeń… - Coordination chemistry …, 2005 - Elsevier
The design and construction of new supramolecular coordination compounds based on
octacyanometalate [M (CN) 8] 3−/4−(M= Mo and W) building blocks of potential utility as …

Symmetry-Based Magnetic Anisotropy in the Trigonal Bipyramidal Cluster [Tp2(Me3tacn)3Cu3Fe2(CN)6]4+

CF Wang, JL Zuo, BM Bartlett, Y Song… - Journal of the …, 2006 - ACS Publications
Reaction of [(Me3tacn) Cu (H2O) 2] 2+(Me3tacn= N, N ', N ''-trimethyl-1, 4, 7-
triazacyclononane) with [TpFe (CN) 3]-(Tp-= hydrotris (pyrazolyl) borate) in a mixture of …

Ferromagnetic Coupling between Low-and High-Spin Iron (III) Ions in the Tetranuclear Complex f ac-{[FeIII {HB (pz) 3}(CN) 2 (μ-CN)] 3FeIII (H2O) 3}⊙ 6H2O ([HB (pz) …

R Lescouëzec, J Vaissermann, F Lloret… - Inorganic …, 2002 - ACS Publications
The novel mononuclear PPh4-fac-[FeIII {HB (pz) 3}(CN) 3]⊙ H2O (1)[PPh4+=
tetraphenylphosphonium cation;(HB (pz) 3)-= hydrotris (1-pyrazolyl) borate] and tetranuclear …

Heterotrimetallic Coordination Polymers: {CuIILnIIIFeIII} Chains and {NiIILnIIIFeIII} Layers: Synthesis, Crystal Structures, and Magnetic Properties

MG Alexandru, D Visinescu, M Andruh… - … A European Journal, 2015 - Wiley Online Library
The use of the [FeIII (AA)(CN) 4]− complex anion as metalloligand towards the preformed
[CuII (valpn) LnIII] 3+ or [NiII (valpn) LnIII] 3+ heterometallic complex cations (AA= 2, 2 …

Cyanide-bridged assemblies constructed from capped tetracyanometalate building blocks [MA (ligand)(CN) 4] 1−/2−(MA= Fe or Cr)

YH Li, WR He, XH Ding, S Wang, LF Cui… - Coordination Chemistry …, 2012 - Elsevier
The design and synthesis of cyanide-bridged heterometallic molecular assemblies via self-
assembly of capped tetracyanometalate [MA (L)(CN) 4] n−(MA= FeIII/II, CrIII, L= bidentate …

Chiral Cyanide-Bridged CrIII–MnIII Heterobimetallic Chains Based on [(Tp)Cr(CN)3]: Synthesis, Structures, and Magnetic Properties

MX Yao, Q Zheng, XM Cai, YZ Li, Y Song… - Inorganic …, 2012 - ACS Publications
By the reactions of MnIII Schiff-base complexes with the tricyanometalate building block,[(Tp)
Cr (CN) 3]−(Tp= Tris (pyrazolyl) hydroborate), two couples of enantiomerically pure chiral …