Review on the use of heavy metal deposits from water treatment waste towards catalytic chemical syntheses

TK Das, A Poater - International Journal of Molecular Sciences, 2021 - mdpi.com
The toxicity and persistence of heavy metals has become a serious problem for humans.
These heavy metals accumulate mainly in wastewater from various industries' discharged …

Predictive catalysis: a valuable step towards machine learning

R Monreal-Corona, A Pla-Quintana, A Poater - Trends in Chemistry, 2023 - cell.com
As physical chemistry transitioned to computational chemistry, a new growth occurred in the
field with the advent of predictive catalysis, making it a key player in the optimization and …

Iron-catalysed ring-opening metathesis polymerization of olefins and mechanistic studies

S Takebayashi, MA Iron, M Feller… - Nature …, 2022 - nature.com
The olefin metathesis reaction is among the most widely applicable catalytic reactions for
carbon–carbon double bond formation. Currently, Mo–and Ru–carbene catalysts are the …

Mechanistic Insights into the cis-Selective Catalytic Ring-Opening Metathesis Polymerization

I Mandal, AFM Kilbinger - Journal of the American Chemical …, 2024 - ACS Publications
Cis-selective ring-opening metathesis polymerization (ROMP) with the commercial Grubbs
“nitrato catalyst” has shown promise for synthesizing stereoregular materials, but it comes …

Iron‐Catalyzed Olefin Metathesis: Recent Theoretical and Experimental Advances

BW Grau, A Neuhauser, S Aghazada… - … A European Journal, 2022 - Wiley Online Library
The “metathesis reaction” is a straightforward and often metal‐catalyzed chemical reaction
that transforms two hydrocarbon molecules to two new hydrocarbons by exchange of …

Stereoselective Diels–Alder Reactions of gem-Diborylalkenes: Toward the Synthesis of gem-Diboron-Based Polymers

N Eghbarieh, N Hanania, A Zamir… - Journal of the …, 2021 - ACS Publications
Although gem-diborylalkenes are known to be among the most valuable reagents in modern
organic synthesis, providing a rapid access to a wide array of transformations, including the …

Deconstruction of Polymers through Olefin Metathesis

D Sathe, S Yoon, Z Wang, H Chen, J Wang - Chemical Reviews, 2024 - ACS Publications
The consumption of synthetic polymers has ballooned; so has the amount of post-consumer
waste generated. The current polymer economy, however, is largely linear with most of the …

Metal‐Free Ring‐Opening Metathesis Polymerization with Hydrazonium Initiators

PK Quach, JH Hsu, I Keresztes, BP Fors… - Angewandte …, 2022 - Wiley Online Library
The ring‐opening metathesis polymerization (ROMP) of cyclopropenes using hydrazonium
initiators is described. The initiators, which are formed by the condensation of 2, 3 …

Olefin Metathesis by First‐Row Transition Metals

DS Belov, G Tejeda, KV Bukhryakov - ChemPlusChem, 2021 - Wiley Online Library
Catalytic olefin metathesis based on the second‐and third‐row transition metals has
become one of the most powerful transformations in modern organic chemistry. The shift to …

Vanadium imido NHC complexes for ring-closing olefin metathesis reactions

G Tejeda, DS Belov, DA Fenoll, KL Rue, C Tsay… - …, 2022 - ACS Publications
Vanadium bis-phosphine imido and oxo chloride alkylidenes have been extensively applied
in the ring-closing metathesis of various acyclic olefins. However, their reactions involving …