Covalent Attachment of Cobalt Bis (Benzylaminedithiolate) to Reduced Graphene Oxide as a Thin-Film Electrocatalyst for Hydrogen Production with Remarkable …

VA Larson, N Lehnert - ACS Catalysis, 2023 - ACS Publications
Hydrogen (H2) can be produced in the water splitting reaction, specifically on the cathodic
side through the hydrogen evolution reaction (HER), where two protons and two electrons …

[HTML][HTML] Electrochemistry and electrocatalysis of H2 generation using hexacoordinated nickel—based complexes

IO Shotonwa, O Ejeromedoghene, AO Adesoji… - Catalysis …, 2023 - Elsevier
Catalysts based on first-row transition series complexes have been extensively utilized for
electrocatalytic H 2 generation and among them are molecular nickel catalysts which have …

Exploring the Performance of Biocatalysts for Biohydrogen Production

C Pandit, M Kumar, RC Kuhad, K Sharma, A Roy… - Biocatalysis and …, 2024 - Elsevier
Biohydrogen production, a feasible and environmentally friendly energy source, has
advanced, notably in biocatalysts. This research carefully examines biocatalysts for …

Catalyst Protonation Changes the Mechanism of Electrochemical Hydride Transfer to CO2

KYC Lee, DE Polyansky, DC Grills… - ACS Organic & …, 2024 - ACS Publications
It is well-known that addition of a cationic functional group to a molecule lowers the
necessary applied potential for an electron transfer (ET) event. This report studies the effect …

Hydrogen production based on hexacoordinated cobalt scaffolds as electrocatalysts for acid-proton reduction: Electrochemistry and mechanisms

IO Shotonwa, O Ejeromedoghene, AO Adesoji… - Journal of …, 2024 - Elsevier
The production of hydrogen as a fuel from the electrocatalytic reduction of protons is fast
becoming a pivotal requirement for the future hydrogen economy that will provide lasting …

Electrocatalytic reduction of protons with bis (N-para-carboxyphenyldithiocarbamato)-(1, 10-phenanthroline) cobalt (II) and manganese (II) complexes

IO Shotonwa, B Kpomah, BM Durodola… - Journal of …, 2024 - Elsevier
Abstract In this study, 1, 10-phenanthroline adducts of bis (N-para-
carboxyphenyldithiocarbamato)-cobalt (II)(1) and manganese (II)(2) possessing Co II/I and …

The Hydrogen Evolution Reaction: Using Molecular Design in Transition Metal Complexes to Control Catalytic Microenvironments on Electrode Surfaces

L Trowbridge, PE Sues - ChemCatChem, 2024 - Wiley Online Library
Hydrogen gas and its production from renewable power sources will be an important part of
decreasing global reliance on fossil fuels and developing a sustainable energy economy …

N‒N hydrazonyl bond cleavage in benzothiazolyl-hydrazino-phenathrenequinone mediated by ruthenium (II) via an anion radical intermediate

G Kanrar, S Halder, S Naskar, D Jana, A Sarkar… - Journal of Molecular …, 2024 - Elsevier
Abstract The complexes [Ru (L Benz) H (CO)(PPh 3) 2] 2,[Ru (L Benz) Cl (CO)(PPh 3) 2]
3,(ligand behaving as bidentate monoanionic) and [Ru (L Benz) Cl (CO)(PPh 3)] 4,(ligand is …

Earth Abundant Transition Metal Molecular Complexes for Water Splitting

V Larson - 2024 - deepblue.lib.umich.edu
Further development and understanding of the chemistry of earth-abundant transition-metal
molecular catalysts for water splitting will aid development of a sustainable hydrogen …