Catalytic applications of vanadium: a mechanistic perspective

RR Langeslay, DM Kaphan, CL Marshall… - Chemical …, 2018 - ACS Publications
The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present
review, reactions catalyzed by homogeneous and supported vanadium complexes from …

Chemistry with methane: concepts rather than recipes

H Schwarz - Angewandte Chemie International Edition, 2011 - Wiley Online Library
Four seemingly simple transformations related to the chemistry of methane will be
addressed from mechanistic and conceptual points of view: 1) metal‐mediated …

Universality in oxygen evolution electrocatalysis on oxide surfaces

IC Man, HY Su, F Calle‐Vallejo, HA Hansen… - …, 2011 - Wiley Online Library
Trends in electrocatalytic activity of the oxygen evolution reaction (OER) are investigated on
the basis of a large database of HO* and HOO* adsorption energies on oxide surfaces. The …

Role of ceria in oxidative dehydrogenation on supported vanadia catalysts

MV Ganduglia-Pirovano, C Popa, J Sauer… - Journal of the …, 2010 - ACS Publications
The effect of the suppport on oxidative dehydrogenation activity for vanadia/ceria systems is
examined for the oxidation of methanol to formaldehyde by use of well-defined VO x/CeO2 …

Support effect in oxide catalysis: methanol oxidation on vanadia/ceria

T Kropp, J Paier, J Sauer - Journal of the American Chemical …, 2014 - ACS Publications
Density functional theory is used for periodic models of monomeric vanadia species
deposited on the CeO2 (111) surface to study dissociative adsorption of methanol and its …

Structure, Optical, and Catalytic Properties of Novel Hexagonal Metastable h-MoO3 Nano- and Microrods Synthesized with Modified Liquid-Phase Processes

W Pan, R Tian, H Jin, Y Guo, L Zhang, X Wu… - Chemistry of …, 2010 - ACS Publications
Single crystalline h-MoO3 nano-and microrods were successfully synthesized using
modified liquid-phase processes with concentrated HNO3 and H2SO4. Their X-ray powder …

Chemie mit Methan: Studieren geht über Probieren!

H Schwarz - Angewandte Chemie, 2011 - Wiley Online Library
Konzeptionelle Überlegungen zu und mechanistische Aspekte von vier scheinbar einfachen
chemischen Umsetzungen, die in der Chemie von Methan von Bedeutung sind, werden in …

A review and experimental revisit of alternative catalysts for selective oxidation of methanol to formaldehyde

J Thrane, UV Mentzel, M Thorhauge, M Høj, AD Jensen - Catalysts, 2021 - mdpi.com
The selective oxidation of methanol to formaldehyde is a growing million-dollar industry, and
has been commercial for close to a century. The Formox process, which is the largest …

Selective oxidation of methanol to dimethoxymethane on V2O5–MoO3/γ-Al2O3 catalysts

Y Meng, T Wang, S Chen, Y Zhao, X Ma… - Applied Catalysis B …, 2014 - Elsevier
This paper describes the design and application of V 2 O 5–MoO 3/Al 2 O 3 catalysts for the
selective oxidation of methanol to dimethoxymethane (DMM). The V 2 O 5–MoO 3/Al 2 O 3 …

The non-innocent role of cerium oxide in heterogeneous catalysis: A theoretical perspective

MV Ganduglia-Pirovano - Catalysis Today, 2015 - Elsevier
Ceria (CeO 2) is the most significant of the oxides of rare-earth elements in industrial
catalysis with its reducibility being essential to its functionality in catalytic applications. The …