Carbene transfer from triazolylidene gold complexes as a potent strategy for inducing high catalytic activity
D Canseco-Gonzalez, A Petronilho… - Journal of the …, 2013 - ACS Publications
A series of gold (I) complexes [AuCl (trz)] were synthesized that contain 1, 2, 3-triazolylidene
(trz) ligands with variable wingtip groups. In the presence of AgBF4, these complexes …
(trz) ligands with variable wingtip groups. In the presence of AgBF4, these complexes …
Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes
A straightforward synthetic route has been developed permitting the formation of homoleptic
and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven …
and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven …
From Stiba-and Bismaheteroboroxines to N, C, N-Chelated Diorganoantimony (III) and Bismuth (III) Cations An Unexpected Case of Aryl Group Migration
L Dostal, R Jambor, A Ruzicka, R Jirasko… - Inorganic …, 2015 - ACS Publications
An unprecedented transfer of an aryl group from boron to Sb and Bi is observed in the
reaction of heteroboroxines of general formula ArM [(OBR) 2O][where M= Sb, Bi; Ar= C6H3 …
reaction of heteroboroxines of general formula ArM [(OBR) 2O][where M= Sb, Bi; Ar= C6H3 …
Inner-Sphere versus Outer-Sphere Coordination of BF4– in a NHC-Gold(I) Complex
RMP Veenboer, A Collado, S Dupuy, T Lebl… - …, 2017 - ACS Publications
The role of counterions in chemistry mediated by gold complexes stretches much further
than merely providing charge balance to cationic gold species. Interplay between their …
than merely providing charge balance to cationic gold species. Interplay between their …
Organometallic Iridium Complex Containing a Dianionic, Tridentate, Mixed Organic–Inorganic Ligand
AJ Bloomfield, AJ Matula, BQ Mercado… - Inorganic …, 2016 - ACS Publications
A pentamethylcyclopentadienyl–iridium complex containing a tricyclic, dianionic, tridentate,
scorpionate (facial binding), mixed organic–inorganic ligand was synthesized and …
scorpionate (facial binding), mixed organic–inorganic ligand was synthesized and …
Fundamental Reactions for Gold Catalysis
J Gubler - 2019 - research-collection.ethz.ch
Successful design of catalytic processes profits form comprehensive understanding of the
kinetics and thermodynamics of fundamental reactions. Potential elementary reactions of …
kinetics and thermodynamics of fundamental reactions. Potential elementary reactions of …