Bio-based polymers with performance-advantaged properties

RM Cywar, NA Rorrer, CB Hoyt, GT Beckham… - Nature Reviews …, 2022 - nature.com
Bio-based compounds with unique chemical functionality can be obtained through selective
transformations of plant and other non-fossil, biogenic feedstocks for the development of …

Defining the macromolecules of tomorrow through synergistic sustainable polymer research

FM Haque, JSA Ishibashi, CAL Lidston, H Shao… - Chemical …, 2022 - ACS Publications
Transforming how plastics are made, unmade, and remade through innovative research and
diverse partnerships that together foster environmental stewardship is critically important to …

Chemical recycling to monomer for an ideal, circular polymer economy

GW Coates, YDYL Getzler - Nature Reviews Materials, 2020 - nature.com
The majority of post-consumer plastic waste is not recycled. Impediments to the recycling of
commodity polymers include separation, impurities and degradation of the macromolecular …

Synthesis, life cycle assessment, and polymerization of a vanillin-based spirocyclic diol toward polyesters with increased glass-transition temperature

SV Mankar, MN Garcia Gonzalez… - ACS Sustainable …, 2019 - ACS Publications
Bio-based rigid diols are key building blocks in the development and preparation of high-
performance bioplastics with improved thermal and dimensional stabilities. Here, we report …

Sequence control from mixtures: switchable polymerization catalysis and future materials applications

AC Deacy, GL Gregory, GS Sulley… - Journal of the …, 2021 - ACS Publications
There is an ever-increasing demand for higher-performing polymeric materials
counterbalanced by the need for sustainability throughout the life cycle. Copolymers …

CO 2-fixation into cyclic and polymeric carbonates: principles and applications

AJ Kamphuis, F Picchioni, PP Pescarmona - Green chemistry, 2019 - pubs.rsc.org
The reaction between carbon dioxide and epoxides is an attractive pathway for CO2-
utilisation as it can lead to the formation of two different, yet valuable, products: cyclic and …

Catalysis as an enabling science for sustainable polymers

X Zhang, M Fevre, GO Jones, RM Waymouth - Chemical reviews, 2018 - ACS Publications
The replacement of current petroleum-based plastics with sustainable alternatives is a
crucial but formidable challenge for the modern society. Catalysis presents an enabling tool …

Sustainable polymers from renewable resources

Y Zhu, C Romain, CK Williams - Nature, 2016 - nature.com
Renewable resources are used increasingly in the production of polymers. In particular,
monomers such as carbon dioxide, terpenes, vegetable oils and carbohydrates can be used …

Fatty acids and their derivatives as renewable platform molecules for the chemical industry

U Biermann, UT Bornscheuer… - Angewandte Chemie …, 2021 - Wiley Online Library
Oils and fats of vegetable and animal origin remain an important renewable feedstock for the
chemical industry. Their industrial use has increased during the last 10 years from 31 to 51 …

Progress of polymers from renewable resources: furans, vegetable oils, and polysaccharides

A Gandini, TM Lacerda, AJF Carvalho… - Chemical …, 2016 - ACS Publications
The interest in polymers from renewable resources has been witnessing an incessant
growth in both academia and industry, with these blooming activities covering a …