The CcCR quartic force field (QFF) methodology is capable of computing B 0 and C 0
rotational constants to within 35 MHz (0.14%) of experiment for triatomic and larger …

There has been a rapid development in the study of metal carbonyl cations, which exhibit
distinguishing characteristics in comparison with typical metal carbonyl complexes. This …

The F12-TZ-cCR quartic force field (QFF) methodology, defined here as CCSD (T)-F12b/cc-
pCVTZ-F12 with further corrections for relativity, is introduced as a cheaper and even more …

A hybrid quartic force field approach produces the same accuracies as non‐hybrid methods
but for less than one quarter of the computational time. This method utilizes explicitly …

Thesynthesis and characterization of salts of the cationic silver (I) carbonylcomplexes [Ag
(CO)]+ and [Ag (CO) 2]+ are reported. The counterions used include OTeF5* and the weakly …

The syntheses, spectroscopy, and structures of silver (I) hydrotris (3, 5-bis (trifluoromethyl)
pyrazolyl) borate complexes with tetrahydrofuran (THF), toluene, carbon monoxide …

In addition to the numerous and varied examples of organometallic and coordination
compounds where carbon monoxide functions as a π-acceptor ligand, there is a small but …

The Th3+ complex,(C5Me5) 3Th, has been isolated despite the fact that tris (
pentamethylcyclopentadienyl) complexes are highly reactive due to steric crowding and few …

We present experimental evidence for nuclear spin selection rules in chemical reactions that
have been theoretically anticipated by Quack [M. Quack, Mol. Phys. 34, 477 (1997)]. The …

The ν3 (N–N or C–O stretch) fundamental bands of HN+ 2, DN+ 2, and DCO+ in the 5 μm
region have been studied using a tunable infrared diode laser source. The absorption cell …