Conclusions This review demonstrates that cobalt enantioselective catalysis is growing
rapidly in almost all spheres of asymmetric organic transformations owing to the unique …

The development of facile synthetic methods for stereodefined aliphatic cyclic amines is an
important research field in synthetic organic chemistry since such scaffolds constitute a …

The asymmetric desymmetrization of meso‐2‐alkynylbenzenediols through the use of a
combination of axially chiral diphosphine (AuCl) 2 precatalysts and silver salt co‐catalysts …

A new, sequential proline-catalyzed approach to the synthesis of (+)-L-733,060 and (+)-T-
2328 in high optical purity (93% ee) is described starting from phenyl N-Boc imine. The …

An efficient diastereoselective approach to access trans-5-hydroxy-6-substituted 2-
piperidinones skeleton has been developed through one-pot intramolecular tandem process …

An efficient diastereoselective approach to access trans-5-hydroxy-6-substitutedethanone-2-
piperidinones skeleton has been developed through sequential addition-deprotection …

The Co (III)(salen) OAc-catalyzed two stereocentered hydrolytic kinetic resolution (HKR) of
anti-β, β′-diphenylmethyloxirane and anti-3-phenylethyloxiranes affords the corresponding …

An enantiopure piperidine, a key intermediate for the synthesis of (+)-tofacitinib, has been
achieved in high optical purity (98% ee) from readily available crotyl alcohol. The key steps …

By the very fact of the lower costs and toxicity of cobalt catalysts in comparison with other
transition metals, sustainable cobalt‐mediated transformations have received a growing …

A short synthetic sequence to rac-5‑hydroxy‑6-hydroxymethylpiperidin-2-one, a useful
intermediate in the synthesis of polyhydroxylated piperidine alkaloids, was based on the …