Photoelectron photoion coincidence spectroscopy provides mechanistic insights in fuel synthesis and conversion

P Hemberger, A Bodi, T Bierkandt, M Köhler… - Energy & …, 2021 - ACS Publications
Clean combustion, ie, the reduction of NOx and soot emissions, and carbon neutrality,
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …

Possible use as biofuels of monoaromatic oxygenates produced by lignin catalytic conversion: A review

F Battin-Leclerc, N Delort, I Meziane, O Herbinet… - Catalysis Today, 2023 - Elsevier
Small aromatic molecules with oxygen-containing functional groups (monoaromatic
oxygenates) are common products of the catalytic depolymerization of lignin, which can be …

An experimental and modeling investigation of the combustion of anisole and guaiacol

N Delort, I Meziane, M Framinet, R Bounaceur… - Fuel, 2024 - Elsevier
Anisole and guaiacol are both used as surrogates for lignin-derived biofuel. However, while
the oxidation reaction mechanisms of anisole can be validated against a large set of …

Synergistic effects of ether oxygen bond/benzene ring and hydrocarbon chain structure on soot morphology and nanostructure

W Dong, R Hong, S Feng, B Qiu, R Fang, H Chu - Fuel, 2025 - Elsevier
Anisole contains ether oxygen bond, toluene has benzene ring structure, and n-heptane has
hydrocarbon chain structure. This research was to study the synergistic effects of ether …

Experimental and kinetic modeling investigation on anisole pyrolysis: Implications on phenoxy and cyclopentadienyl chemistry

W Yuan, T Li, Y Li, M Zeng, Y Zhang, J Zou, C Cao… - Combustion and …, 2019 - Elsevier
In this work, the flow reactor pyrolysis of anisole was studied at pressures of 0.04 and 1 atm
and temperatures from 850 to 1160 K. Comprehensive speciation was achieved using …

Formation of PAHs, phenol, benzofuran, and dibenzofuran in a flow reactor from the oxidation of ethylene, toluene, and n-decane

S Suzuki, G Kukkadapu, S Kiuchi, SW Wagnon… - Combustion and …, 2022 - Elsevier
The necessity to reveal the formation mechanism of not only polycyclic aromatic
hydrocarbons (PAHs) but also oxygenated PAHs (OPAHs) during combustion is increasing …

Isomer-sensitive characterization of low temperature oxidation reaction products by coupling a jet-stirred reactor to an electron/ion coincidence spectrometer: case of n …

J Bourgalais, Z Gouid, O Herbinet, GA Garcia… - Physical Chemistry …, 2020 - pubs.rsc.org
Through the use of tunable vacuum ultraviolet light generated by the DESIRS VUV
synchrotron beamline, a jet-stirred reactor was coupled for the first time to an advanced …

Investigation of the combustion chemistry in laminar, low-pressure oxymethylene ether flames (OME0–4)

N Gaiser, H Zhang, T Bierkandt, S Schmitt… - Combustion and …, 2022 - Elsevier
Quantitative speciation data for alternative fuels is highly desired to assess their emission
potential and to develop and validate chemical kinetic models. In terms of substitute choices …

Oxidation of oxymethylene ether (OME0− 5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy

N Gaiser, T Bierkandt, P Oßwald, J Zinsmeister… - Fuel, 2022 - Elsevier
This paper presents a systematic study of oxymethylene ethers (OMEs) oxidation in an
atmospheric laminar flow reactor setup. Oxymethylene ethers with different number of …

The threshold photoelectron spectrum of fulvenone: a reactive ketene derivative in lignin valorization

P Hemberger, Z Pan, A Bodi… - …, 2020 - Wiley Online Library
Unveiling reaction mechanisms by isomer‐selective detection of reactive intermediates
requires advanced spectroscopic knowledge. We study the photoionization of fulvenone (c …