Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Recent applications of C–H functionalization in complex natural product synthesis

DJ Abrams, PA Provencher, EJ Sorensen - Chemical Society Reviews, 2018 - pubs.rsc.org
In this review, recent examples featuring C–H functionalization in the synthesis of complex
natural products are discussed. A focus is given to the way in which C–H functionalization …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Towards mild metal-catalyzed C–H bond activation

J Wencel-Delord, T Dröge, F Liu… - Chemical Society Reviews, 2011 - pubs.rsc.org
Functionalizing traditionally inert carbon–hydrogen bonds represents a powerful
transformation in organic synthesis, providing new entries to valuable structural motifs and …

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

L McMurray, F O'Hara, MJ Gaunt - Chemical Society Reviews, 2011 - pubs.rsc.org
Metal-catalysed C–H bond functionalisation has had a significant impact on how chemists
make molecules. Translating the methodological developments to their use in the assembly …

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

R Giri, BF Shi, KM Engle, N Maugel… - Chemical Society Reviews, 2009 - pubs.rsc.org
This critical review discusses historical and contemporary research in the field of transition
metal-catalyzed carbon–hydrogen (C–H) bond activation through the lens of …

Functionalization of Organic Molecules by Transition‐Metal‐Catalyzed C(sp3)H Activation

R Jazzar, J Hitce, A Renaudat… - … A European Journal, 2010 - Wiley Online Library
Transition‐metal‐catalyzed C H activation has recently emerged as a powerful tool for the
functionalization of organic molecules. While many efforts have focused on the …

General regio-and diastereoselective allylic C–H oxygenation of internal alkenes

K Yamada, KPS Cheung… - Journal of the American …, 2024 - ACS Publications
Branched allylic esters and carboxylates are fundamental motifs prevalent in natural
products and drug molecules. The direct allylic C–H oxygenation of internal alkenes …

C H Activation: A Complementary Tool in the Total Synthesis of Complex Natural Products

DYK Chen, SW Youn - Chemistry–A European Journal, 2012 - Wiley Online Library
The recent advent of transition‐metal mediated C H activation is revolutionizing the
synthetic field and gradually infusing a “C H activation mind‐set” in both students and …

A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral α-aryl alkylboronates

Y Zhang, J Ma, J Chen, L Meng, Y Liang, S Zhu - Chem, 2021 - cell.com
Ligand-controlled reactivity plays an important role in transition-metal catalysis, enabling a
vast number of efficient transformations to be discovered and developed. However, a single …