The Pd‐catalyzed coupling of aryl (pseudo) halides and amines is one of the most powerful
approaches for the formation of C (sp2)− N bonds. The pioneering reports from Migita and …

Pd-catalyzed amination reaction of aryl halides has attracted much attention in recent years.
This review underscores selected important recent developments in the catalysis of one of …

Deactivation leads to loss of catalyst activity or selectivity with increasing reaction time, but
has attracted less academic attention in homogeneous catalysis than is justified by its …

Collectively, palladium‐catalyzed coupling reactions represent some of the most powerful
and versatile tools available to synthetic organic chemists. Their widespread popularity …

Single-atom catalysts (SACs) open up new possibilities for advanced technologies.
However, a major complication in preparing high-density single-atom sites is the …

Selective aerobic oxidation of organic molecules is a fundamental and practical challenge in
modern chemistry. Effective solutions to this problem must overcome the intrinsic reactivity …

Organomagnesium reagents occupy a central position in synthetic organic and
organometallic chemistry. Recently, the halogen–magnesium exchange has considerably …

The palladium-catalysed arylation of an alkene with an organic halide (Scheme 1) was first
reported by Mizoroki1 and Heck2 in the early 1970s. The classical reaction involves bond …

The complexes trans-RuH (Cl)(tmen)(R-binap)(1) and (OC-6− 43)-RuH (Cl)(tmen)(PPh3) 2
(2) are prepared by the reaction of the diamine NH2CMe2CMe2NH2 (tmen) with RuH …

Palladiumkatalysierte Kupplungen gehören zu den leistungsfähigsten und vielseitigsten
Reaktionen, die dem organischen Chemiker für die Synthese zur Verfügung stehen. Ihre …