Boron hydrogen compounds: hydrogen storage and battery applications

H Hagemann - Molecules, 2021 - mdpi.com
About 25 years ago, Bogdanovic and Schwickardi (B. Bogdanovic, M. Schwickardi: J. Alloys
Compd. 1–9, 253 (1997) discovered the catalyzed release of hydrogen from NaAlH4. This …

Calcium Hydride Cation [CaH]+ Stabilized by an NNNN‐type Macrocyclic Ligand: A Selective Catalyst for Olefin Hydrogenation

D Schuhknecht, C Lhotzky, TP Spaniol… - Angewandte Chemie …, 2017 - Wiley Online Library
Reaction of dibenzyl calcium complex [Ca (Me4TACD)(CH2Ph) 2], containing the neutral
NNNN‐type macrocyclic ligand Me4TACD (Me4TACD= 1, 4, 7, 10‐tetramethyl‐1, 4, 7, 10 …

Closo-hydroborate sodium salts as an emerging class of room-temperature solid electrolytes

M Brighi, F Murgia, R Černý - Cell Reports Physical Science, 2020 - cell.com
Na-based hydroborates, such as NaCB 9 H 10, Na 2 B 10 H 10, NaCB 11 H 12, and Na 2 B
12 H 12, are known for their high ionic conductivity above a phase transition, usually far from …

Calcium Borohydride Ca(BH4)2: Fundamentals, Prediction and Probing for High-Capacity Energy Storage Applications, Organic Synthesis and Catalysis

C Comanescu - Energies, 2023 - mdpi.com
Calcium borohydride (Ca (BH4) 2) is a complex hydride that has been less investigated
compared to its lighter counterpart, magnesium borohydride. While offering slightly lower …

Molecular Calcium Hydride: Dicalcium Trihydride Cation Stabilized by a Neutral NNNN‐Type Macrocyclic Ligand

V Leich, TP Spaniol, L Maron… - Angewandte Chemie …, 2016 - Wiley Online Library
Hydrogenolysis of bis (triphenylsilyl) calcium containing the neutral NNNN‐type macrocyclic
amine ligand Me4TACD [Ca (Me4TACD)(SiPh3) 2](2), gave the cationic dinuclear calcium …

Quantitative Assessment of B−B−B, B−Hb−B, and B−Ht Bonds: From BH3 to B12H122−

D Sethio, LML Daku, H Hagemann, E Kraka - ChemPhysChem, 2019 - Wiley Online Library
We report the thermodynamic stabilities and the intrinsic strengths of three‐center‐two‐
electron B− B− B and B− Hb− B bonds (: bridging hydrogen), and two‐center‐two‐electron …

Calciumhydrid‐Kation [CaH]+ stabilisiert durch einen makrocyclischen NNNN‐Liganden: ein selektiver Katalysator für die Hydrierung von Olefinen

D Schuhknecht, C Lhotzky, TP Spaniol… - Angewandte …, 2017 - Wiley Online Library
Abstract Die Reaktion des Dibenzylcalcium‐Komplexes [Ca (Me4TACD)(CH2Ph) 2],
stabilisiert durch den neutralen, makrocyclischen Liganden 1, 4, 7, 10‐Tetramethyl‐1, 4, 7 …

Effect of additives, ball milling and isotopic exchange in porous magnesium borohydride

M Heere, O Zavorotynska, S Deledda, MH Sørby… - RSC …, 2018 - pubs.rsc.org
Magnesium borohydride (Mg (BH4) 2) is a promising material for solid state hydrogen
storage. However, the predicted reversible hydrogen sorption properties at moderate …

Molekulares Calciumhydrid: Dicalciumtrihydrid‐Kation, stabilisiert durch einen neutralen makrocyclischen NNNN‐Liganden

V Leich, TP Spaniol, L Maron, J Okuda - Angewandte Chemie, 2016 - Wiley Online Library
Abstract Die Hydrierung von Bis (triphenylsilyl) calcium mit dem neutralen makrocyclischen
Aminliganden 1, 4, 7, 10‐Tetramethyl‐1, 4, 7, 10‐tetraazacyclododecan (Me4TACD) vom …

Nuclear Magnetic Resonance Study of Molecular Dynamics in Ammine Metal Borohydride Sr(BH4)2(NH3)2

A Gradišek, LH Jepsen, TR Jensen… - The Journal of …, 2016 - ACS Publications
We investigated molecular dynamics in Sr (BH4) 2 (NH3) 2, which is a representative
compound for a series of ammine metal borohydrides, a novel family of systems exhibiting …