Understanding electromigration failure behaviors of narrow cobalt lines and the mechanism of reliability enhancement for extremely dilute alloying of manganese …

JS Fang, GS Chen, CC Chang, CN Hsiao… - Journal of Alloys and …, 2024 - Elsevier
Self-forming barriers for copper (Cu) interconnect metallization are well developed.
However, the self-forming-barrier process and associated electromigration behaviors of …

In Situ XPS Chemical Analysis of MnSiO3 Copper Diffusion Barrier Layer Formation and Simultaneous Fabrication of Metal Oxide Semiconductor Electrical Test MOS …

C Byrne, B Brennan, AP McCoy, J Bogan… - … applied materials & …, 2016 - ACS Publications
Copper/SiO2/Si metal-oxide-semiconductor (MOS) devices both with and without a MnSiO3
barrier layer at the Cu/SiO2 interface have been fabricated in an ultrahigh vacuum X-ray …

On the use of (3-trimethoxysilylpropyl) diethylenetriamine self-assembled monolayers as seed layers for the growth of Mn based copper diffusion barrier layers

A Brady-Boyd, R O'Connor, S Armini, V Selvaraju… - Applied Surface …, 2018 - Elsevier
In this work x-ray photoelectron spectroscopy is used to investigate in-vacuo, the interaction
of metallic manganese with a (3-trimethoxysilylpropyl) diethylenetriamine (DETA) self …

Reliability of copper low-k interconnects

Z Tőkei, K Croes, GP Beyer - Microelectronic Engineering, 2010 - Elsevier
For the implementation of copper and low-k materials into a tight pitch damascene
interconnect architecture it is important to understand and correctly describe the underlying …

Reversible and cyclical transformations between solid and hollow nanostructures in confined reactions of manganese oxide and silica within nanosized spheres

TL Ha, JG Kim, SM Kim, IS Lee - Journal of the American …, 2013 - ACS Publications
Annealing of MnO@ SiO2 nanospheres in a reducing gas environment resulted in the
transformation of the core–shell structure into a hollow structure as a result of outward …

Graded composition and valence states in self-forming barrier layers at Cu–Mn/SiO2 interface

Y Otsuka, J Koike, H Sako, K Ishibashi… - Applied Physics …, 2010 - pubs.aip.org
A self-forming diffusion barrier (SFB) layer was formed at Cu–Mn/SiO 2 interface. Spatial
variation of the chemical composition and valence state of the elements in the SFB was …

Interdiffusion and barrier layer formation in thermally evaporated Mn/Cu heterostructures on SiO2 substrates

JG Lozano, S Lozano-Perez, J Bogan… - Applied Physics …, 2011 - pubs.aip.org
Mn/Cu heterostructures thermally evaporated onto SiO 2 and, subsequently, annealed were
investigated by transmission electron microscopy related techniques in order to study the …

Structural and electronic properties of a Mn oxide diffusion barrier layer formed by chemical vapor deposition

VK Dixit, K Neishi, N Akao… - IEEE Transactions on …, 2011 - ieeexplore.ieee.org
A diffusion barrier layer of a few nanometers in thickness is required for a Cu/SiO_2
interconnect structure for advanced integrated circuits (ICs). This paper reports a new barrier …

Effects of Adsorbed Moisture in SiO2 Substrates on the Formation of a Mn Oxide Layer by Chemical Vapor Deposition

N Mai Phuong, K Neishi, Y Sutou… - The Journal of Physical …, 2011 - ACS Publications
Manganese oxide formed by a chemical vapor deposition (CVD) method is a promising
candidate for an ultrathin diffusion barrier layer in the interconnect structure of advanced …

Chemical and structural investigation of the role of both Mn and Mn oxide in the formation of manganese silicate barrier layers on SiO2

P Casey, J Bogan, JG Lozano, PD Nellist… - Journal of Applied …, 2011 - pubs.aip.org
In this study, Mn silicate (MnSiO 3) barrier layers were formed on thermally grown SiO 2
using both metallic Mn and oxidized Mn films, in order to investigate the role of oxygen in …