Glycosyl radical functionalization is one of the central topics in synthetic carbohydrate
chemistry. Recent advances in metal‐catalyzed cross‐coupling chemistry and …

Comprehensive Summary C‐Glycosides are critical, naturally occurring products and
medicinal candidates, and extensive efforts have been made to explore efficient approaches …

A visible-light-induced glycoarylation of activated olefins has been accomplished. Glycosyl
radicals are generated via radical transfer strategies between (TMS) 3SiOH and glycosyl …

Conjugation of carbohydrates to ferrocene scaffolds is of great value in drug design, given
the nontoxic and lipophilic nature of ferrocene. However, the efficient and stereoselective …

A mild approach to the visible-light-mediated bimetal-catalyzed meta-alkylation of arenes
has been accomplished. The regioselective meta-alkylation is realized by a bimetallic …

Glycosyl donor activation emerged as an enabling technology for anomeric
functionalization, but aimed primarily at O-glycosylation. In contrast, we herein disclose …

Organosilicons are privileged skeletons in the domains of pharmaceutical chemistry, organic
synthesis, and materials science. Hence, investigating catalytic techniques for the synthesis …

New glycogen reagents of dioxazolone glycogen anomers have been developed. The
versatile heteroarene C-glycosides have been synthesized using a Ru-catalyzed C–H …

C-Oligosaccharides are metabolically stable surrogates of native glycans containing O/N/S-
glycosidic linkages and thus have therapeutic potential. Here we report a straightforward …

C-Alkyl glycosides, an important class of C-glycosides, are widely found in various drugs
and natural products. The synthesis of C-alkyl glycosides has attracted considerable …