o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors

J Shi, L Li, Y Li - Chemical Reviews, 2021 - ACS Publications
Arynes are among the most active organic intermediates and have found numerous
applications in expeditious preparation of substituted arenes. In the past 20 years, chemists …

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

A Bhunia, SR Yetra, AT Biju - Chemical Society Reviews, 2012 - pubs.rsc.org
This tutorial review is aimed at highlighting recent developments in transition-metal-free
carbon–carbon and carbon–heteroatom bond-forming reactions utilizing a versatile class of …

Use of benzynes for the synthesis of heterocycles

AV Dubrovskiy, NA Markina, RC Larock - Organic & Biomolecular …, 2013 - pubs.rsc.org
About two decades after Kobayashi's discovery in 1983 of a very mild way of generating
highly reactive aryne intermediates, the synthetic community embraced o-(trimethylsilyl) aryl …

Recent advances in molecular rearrangements involving aryne intermediates

T Roy, AT Biju - Chemical Communications, 2018 - pubs.rsc.org
This Feature Article is aimed at highlighting the recent developments in the transition-metal-
free molecular rearrangements involving arynes. The chemistry of arynes has shown …

A closer look at aryne chemistry: details that remain mysterious

C Wu, F Shi - Asian Journal of Organic Chemistry, 2013 - cir.nii.ac.jp
抄録< jats: title> Abstract</jats: title>< jats: p> Recent studies of aryne chemistry have left
some unexplained details in their reactivity, reaction mechanisms, and structure‐activity …

Intermolecular N‐Heterocyclic Carbene Catalyzed Hydroacylation of Arynes

AT Biju, F Glorius - Angewandte Chemie International Edition, 2010 - infona.pl
A formal introduction: The conceptually new N‐heterocyclic carbene catalyzed formal
insertion of arynes into the C formyl H bond of aldehydes demonstrates the compatibility of …

[PDF][PDF] A Multicomponent Coupling Reaction Induced by Insertion of Arynes into the C O Bond of Formamide

E Yoshioka, S Kohtani, H Miyabe - … Chemie International Edition, 2011 - academia.edu
Aryne compounds are highly reactive intermediates that have been widely used in organic
synthesis.[1, 2] In recent years, studies on aryne-based reactions have achieved some …

Insertion of benzene rings into the amide bond: One-step synthesis of acridines and acridones from aryl amides

DG Pintori, MF Greaney - Organic letters, 2010 - ACS Publications
Insertion of benzene rings into the amide bond using the reactive intermediate benzyne is
described. Aromatic amides undergo smooth insertion when treated with O-triflatophenyl …

Synthetic methods for the generation and preparative application of benzyne

T Kitamura - Australian journal of chemistry, 2010 - CSIRO Publishing
Many methods have been developed for generating benzyne. Convenient and reliable
precursors extensively studied so far involve benzenediazonium-2-carboxylate and o …

Synthesis of heterocyclic systems involving [3, 3]-sigmatropic rearrangements

MS Kobzev, AA Titov, AV Varlamov - Russian Chemical Bulletin, 2021 - Springer
The review summarizes the data on the synthesis of heterocyclic compounds by means of [3,
3]-sigmatropic transformations, which include the Fischer, Claisen, and Cope …