This article reviews the most relevant chemical and structural aspects that influence the spin-
crossover phenomenon (SCO). Special attention is focussed on the recent development of …

One of the most important trends in the spin crossover (SCO) field is focused on the
synthesis of new molecule-based functional materials in which the SCO properties may be …

Metal complexes, of which metal ions have d4–d7 electrons, may exhibit spin conversion by
external stimuli, and they are called spin crossover (SCO) complexes. SCO complexes are …

Dinuclear spin crossover molecules can adopt three different spin-pair states: a fully
diamagnetic low spin state,[LS–LS], with both iron (II) atoms in the LS state; a paramagnetic …

Spin crossover cations have been successfully synthesized in the pores of a mesoporous
robust Metal–Organic Framework (MOF) MIL-100 (Al) through sequential introduction of Fe …

The effect of counter anions on thermally induced manganese (III)-based SCO within the [Mn
(5-F-sal-N-1, 5, 8, 12)] Y family has been investigated. All the complexes are crystallized …

Manganese (III) hexadentate Schiff base complexes ([Mn (sal-N-1, 5, 8, 12)] Y· S, Y= AsF6
(1); Y= SbF6 (2); Y= NO3, S= C2H5OH (3) and Y= Cl (4)) have been investigated to …

The prominent role of intra-and inter-molecular vibrations in the spin crossover phenomenon
is outlined, based on the results obtained by the spin crossover community. The …

The syntheses, structures and magnetic properties of the compounds of formula[FeIII (sal2-
trien)][MnIICrIII (ox) 3]· CH2Cl2 (1; H2sal2-trien= N, N'-disalicylidenetriethylenetetramine …

A new type of one-dimensional organic− inorganic hybrid [M (en) 3] Pb2I6 [M= Mn (1), Fe
(2), Zn (3), Ni (4); en= ethylenediamine] has been obtained and structurally characterized by …