Stereoselective formation of boron-stereogenic organoboron derivatives

A Abdou-Mohamed, C Aupic, C Fournet… - Chemical Society …, 2023 - pubs.rsc.org
Four-coordinate organoboron derivatives present interesting chemical, physical, biological,
electronical, and optical properties. Given the increasing demand for the synthesis of smart …

Recent advances in the construction of tetracoordinate boron compounds

X Li, G Zhang, Q Song - Chemical Communications, 2023 - pubs.rsc.org
Tetracoordinate boron compounds are a highly important class of molecules, which are the
key intermediates in many organoboron-related chemical transformations and have unique …

Catalytic enantioselective construction of chiroptical boron-stereogenic compounds

B Zu, Y Guo, C He - Journal of the American Chemical Society, 2021 - ACS Publications
The construction of main group heteroatom-stereogenic compounds is of great importance
due to their intriguing chemical, physical, biological, and stereoelectronic properties. Despite …

Delocalization effect promoted the indoor air purification via directly unlocking the ring-opening pathway of toluene

W Qu, P Wang, M Gao, J Hasegawa… - Environmental …, 2020 - ACS Publications
The ring-opening process was generally considered as the rate-determining step for
aromatic volatile organic compound photocatalytic degradation. A sophisticated and …

Construction of boron-stereogenic compounds via enantioselective Cu-catalyzed desymmetric B–H bond insertion reaction

G Zhang, Z Zhang, M Hou, X Cai, K Yang, P Yu… - Nature …, 2022 - nature.com
Compared with the well-developed carbon-stereogenic chemistry, the construction of boron-
stereogenic compounds remains undeveloped and challenging. Herein, the previously …

Modular enantioselective assembly of multi-substituted boron-stereogenic BODIPYs

LQ Ren, B Zhan, J Zhao, Y Guo, B Zu, Y Li, C He - Nature Chemistry, 2025 - nature.com
Boron dipyrromethenes (BODIPYs) are some of the most popular and indispensable
tetracoordinate boron compounds and have found widespread applications owing to their …

Mannich reaction derived novel boron complexes with amine-bis (phenolate) ligands: Synthesis, spectroscopy and in vitro/in silico biological studies

A Kilic, L Beyazsakal, M Işık, C Türkeş, A Necip… - Journal of …, 2020 - Elsevier
The amine-bis (phenolate) ligands was prepared through a Mannich reaction utilizing two
equivalents of 2, 4-di-tert-butylphenol or 4-tert-butylphenol, two equivalents of formaldehyde …

Catalytic enantioselective synthesis of boron-stereogenic BODIPYs

B Zu, Y Guo, LQ Ren, Y Li, C He - Nature Synthesis, 2023 - nature.com
Boron dipyrromethenes (BODIPYs) are a class of tetracoordinate boron compounds that
have attracted considerable interest in recent decades due to their excellent spectroscopic …

Chirality Transfer of Stereogenic Boron Centers Enabled by a SN2-Type Mechanism

Y Stöckl, K Gugeler, CM Holzwarth, W Frey… - …, 2024 - ACS Publications
Enantioenriched boron chelates show promising synthetic and luminescent properties;
however, the challenging synthesis makes these compounds scarce. In our earlier work, we …

Enantioenriched Boron C,N‐Chelates via Chirality Transfer

Y Stöckl, EJ Tait, W Frey, S Wegner… - … A European Journal, 2023 - Wiley Online Library
Molecules stereogenic only at tetrahedral boron atoms show great promise for applications,
for example as chiroptical materials, but are scarcely investigated due to their synthetic …