Emergence of palladium (IV) chemistry in synthesis and catalysis

P Sehnal, RJK Taylor, IJS Fairlamb - Chemical reviews, 2010 - ACS Publications
Palladium-catalyzed bond-forming processes (eg, CC, CX, CY; X) F; Y) NR2, OR, SR, etc.)
represent essential tools for the synthetic chemist. A fascinating myriad of adventurous and …

Kinetico-mechanistic studies on CX (X= H, F, Cl, Br, I) bond activation reactions on organoplatinum (II) complexes

M Crespo, M Martinez, SM Nabavizadeh… - Coordination Chemistry …, 2014 - Elsevier
The activation of Csingle bondX bonds in homogeneous systems is a relevant topic in
relation to important catalytic industrial processes involving organic substrates and …

Palladium‐Catalyzed Intermolecular C(sp3)H Amidation

A Iglesias, R Alvarez, AR de Lera, K Muniz - … Chemie International Edition, 2012 - infona.pl
Dual capacity: A new palladium‐catalyzed intermolecular sequence consisting of the C H
activation and amidation of methyl groups relies on N‐fluorobis (phenylsulfonyl) imide …

Mechanisms of C− C and C− H Alkane Reductive Eliminations from Octahedral Pt (IV): Reaction via Five-Coordinate Intermediates or Direct Elimination?

DM Crumpton-Bregel, KI Goldberg - Journal of the American …, 2003 - ACS Publications
The Pt (IV) complexes P2PtMe3R [P2= dppe (PPh2 (CH2) 2PPh2), dppbz (o-PPh2 (C6H4)
PPh2); R= Me, H] undergo reductive elimination reactions to form carbon− carbon or …

Computational insight into nickel‐catalyzed carbon–carbon versus carbon–boron coupling reactions of primary, secondary, and tertiary alkyl bromides

MS Cheung, FK Sheong, TB Marder… - Chemistry–A European …, 2015 - Wiley Online Library
The nickel‐catalyzed alkyl–alkyl cross‐coupling (C C bond formation) and borylation (C
B bond formation) of unactivated alkyl halides reported in the literature show completely …

N− C Cleavage in Pincer PNP Complexes of Palladium

L Fan, L Yang, C Guo, BM Foxman, OV Ozerov - Organometallics, 2004 - ACS Publications
Several new N-methylated diarylamine-based PNP pincer ligands have been prepared. The
synthesis of these ligands is modular and allows incorporation of a variety of substituents …

Phosphapalladacycles: preparation routes

VV Dunina, ON Gorunova - Russian chemical reviews, 2004 - pubs.rsc.org
The review considers methods of synthesis of cyclopalladated compounds of the PC-and
PCP-type including intramolecular activation of the C–H bonds in the P-donor ligands …

Thermal C−H Bond Activation of Benzene, Toluene, and Methane with Cationic [M(X)(bipy)]+ (M = Ni, Pd, Pt; X = CH3, Cl; bipy = 2,2′-bipyridine): A Mechanistic …

B Butschke, H Schwarz - Organometallics, 2011 - ACS Publications
In the thermal gas-phase ion/molecule reactions of the mass-selected cationic 2, 2′-
bipyridine (bipy) complexes [M (CH3)(bipy)]+(M= Ni, Pd, Pt) with benzene and toluene …

[图书][B] Advances in organometallic chemistry

AF Hill, MJ Fink - 2011 - books.google.com
Almost all branches of chemistry and material science now interface with organometallic
chemistry--the study of compounds containing carbon-metal bonds. This widely acclaimed …

A brief introduction to transition metals in unusual oxidation states

WTK Chan, WT Wong - Polyhedron, 2013 - Elsevier
As we celebrate the 100th year since Alfred Werner's Nobel Prize in Chemistry award for his
pioneering work on coordination chemistry, we look back in this review at some of the more …