The mechanism of the conversion of arachidonic acid (AA) 1 into prostaglandin G2
(PGG2)(eq 1) has long fascinated chemists and biochemists alike. In this process, no less …

With crude oil reserves dwindling, the hunt for a sustainable alternative feedstock for fuels
and materials for our society continues to expand. The biorefinery concept has enjoyed both …

Time-resolved photothermal and photoacoustic methods applied to photoinduced processes in
solution Page 1 Chem. Rev. 1992, 92, 1381-1410 1381 Time-Resolved Photothermal and …

Lipoxygenases are mononuclear non-heme iron enzymes that regio-and stereospecifcally
convert 1, 4-pentadiene subunit-containing fatty acids into alkyl peroxides. The rate …

The proton-coupled electron transfer reaction catalyzed by soybean lipoxygenase-1 is
studied with a multistate continuum theory that represents the transferring hydrogen nucleus …

The enthalpy change that occurs in a photoinduced chemical reaction in solution can be
quantified by a relatively simple technique known as photoacoustic calorimetry (PAC), which …

Lipoxygenases (LOs) are mononuclear, non-heme iron enzymes found in both plants and
animals that catalyze the oxidative conversion of 1, 4-diene-containing fatty acids to alkyl …

The dynamical behavior and the temperature dependence of the kinetic isotope effects
(KIEs) are examined for the proton-coupled electron transfer reaction catalyzed by the …

Using experimentally calibrated density functional calculations on models of the active site
of soybean lipoxygenase 1 (SLO-1), insight has been obtained into the coordination …

Clarifying the difference in redox reactivity between the metal oxo and metal hydroxo
moieties for the same redox active metal ion in identical structures and oxidation states, that …