Recent advances in the chemistry and applications of N-heterocyclic carbenes

P Bellotti, M Koy, MN Hopkinson, F Glorius - Nature Reviews Chemistry, 2021 - nature.com
N-Heterocyclic carbenes, despite being isolated and characterized three decades ago, still
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …

N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces

M Koy, P Bellotti, M Das, F Glorius - Nature Catalysis, 2021 - nature.com
Heterogeneous catalysts represent the backbone of many industrial processes and thus
have a considerable societal impact. The active sites of these heterogeneous catalysts are …

Self-assembled monolayers for interfacial engineering in solution-processed thin-film electronic devices: design, fabrication, and applications

M Li, M Liu, F Qi, FR Lin, AKY Jen - Chemical Reviews, 2024 - ACS Publications
Interfacial engineering has long been a vital means of improving thin-film device
performance, especially for organic electronics, perovskites, and hybrid devices. It greatly …

Fundamentals and applications of N-heterocyclic carbene functionalized gold surfaces and nanoparticles

G Kaur, RL Thimes, JP Camden… - Chemical …, 2022 - pubs.rsc.org
The discovery of N-heterocyclic carbenes (NHCs) revolutionized organometallic chemistry
due to their strong metal–ligand bonds. These strong bonds also lend enhanced stability to …

N-heterocyclic carbenes capped metal nanoparticles: An overview of their catalytic scope

M Ghosh, S Khan - ACS Catalysis, 2023 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become the most celebrated ligands in various fields
of chemistry due to their unique electronic properties. 1− 5 Since the first stable N …

Recent advances in the domain of cyclic (alkyl)(amino) carbenes

S Kumar Kushvaha, A Mishra… - Chemistry–An Asian …, 2022 - Wiley Online Library
Isolation of cyclic (alkyl) amino carbenes (cAACs) in 2005 has been a major achievement in
the field of stable carbenes due to their better electronic properties. cAACs and bicyclic …

Stability of N-Heterocyclic Carbene Monolayers under Continuous Voltammetric Interrogation

MA Pellitero, IM Jensen, NL Dominique… - … Applied Materials & …, 2023 - ACS Publications
N-Heterocyclic carbenes (NHCs) are promising monolayer-forming ligands that can
overcome limitations of thiol-based monolayers in terms of stability, surface functionality, and …

Self‐Assembled Monolayers of N‐Heterocyclic Olefins on Au (111)

I Berg, L Schio, J Reitz, E Molteni… - Angewandte Chemie …, 2023 - Wiley Online Library
Self‐assembled monolayers (SAMs) of N‐heterocyclic olefins (NHOs) have been prepared
on Au (111) and their thermal stability, adsorption geometry, and molecular order were …

Controlled growth of ordered monolayers of N-heterocyclic carbenes on silicon

M Franz, S Chandola, M Koy, R Zielinski… - Nature Chemistry, 2021 - nature.com
N-Heterocyclic carbenes (NHCs) are promising modifiers and anchors for surface
functionalization and offer some advantages over thiol-based systems. Because of their …

Growth of N‐heterocyclic carbene assemblies on Cu (100) and Cu (111): from single molecules to magic‐number islands

JJ Navarro, M Das, S Tosoni… - Angewandte Chemie …, 2022 - Wiley Online Library
N‐Heterocyclic carbenes (NHCs) have superior properties as building blocks of self‐
assembled monolayers (SAMs). Understanding the influence of the substrate in the …