Molecular spins for quantum computation

A Gaita-Ariño, F Luis, S Hill, E Coronado - Nature chemistry, 2019 - nature.com
Spins in solids or in molecules possess discrete energy levels, and the associated quantum
states can be tuned and coherently manipulated by means of external electromagnetic …

Molecular single-ion magnets based on lanthanides and actinides: Design considerations and new advances in the context of quantum technologies

SG McAdams, AM Ariciu, AK Kostopoulos… - Coordination Chemistry …, 2017 - Elsevier
Over the past fifteen years or so, the study of f-element single-ion magnets (f-SIMs) has gone
from being a sub-discipline of molecular magnetism to an established field of research in its …

An electrostatic model for the determination of magnetic anisotropy in dysprosium complexes

NF Chilton, D Collison, EJL McInnes… - Nature …, 2013 - nature.com
Understanding the anisotropic electronic structure of lanthanide complexes is important in
areas as diverse as magnetic resonance imaging, luminescent cell labelling and quantum …

Spin states, vibrations and spin relaxation in molecular nanomagnets and spin qubits: a critical perspective

L Escalera-Moreno, JJ Baldoví, A Gaita-Arino… - Chemical …, 2018 - pubs.rsc.org
Very recently the closely related fields of molecular spin qubits, single ion magnets and
single atom magnets have been shaken by unexpected results. We have witnessed a jump …

Large magnetic anisotropy in mononuclear metal complexes

S Gómez-Coca, D Aravena, R Morales… - Coordination Chemistry …, 2015 - Elsevier
This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …

[图书][B] Lanthanides and actinides in molecular magnetism

RA Layfield, M Murugesu - 2015 - books.google.com
The first reference on this rapidly growing topic provides an essential up-to-date guide to
current and emerging trends. A group of international experts has been carefully selected by …

Mononuclear single-molecule magnets: tailoring the magnetic anisotropy of first-row transition-metal complexes

S Gomez-Coca, E Cremades… - Journal of the …, 2013 - ACS Publications
Magnetic anisotropy is the property that confers to the spin a preferred direction that could
be not aligned with an external magnetic field. Molecules that exhibit a high degree of …

Magnetic Blocking at 10 K and a Dipolar-Mediated Avalanche in Salts of the Bis(η8-cyclooctatetraenide) Complex [Er(COT)2]

KR Meihaus, JR Long - Journal of the American Chemical Society, 2013 - ACS Publications
The structures and magnetic properties of [K (18-crown-6)]+(1) and [K (18-crown-6)(THF)
2]+(2) salts of the η8-cyclooctatetraenide sandwich complex [Er (COT) 2]−(COT2 …

Toward molecular 4f single-ion magnet qubits

KS Pedersen, AM Ariciu, S McAdams… - Journal of the …, 2016 - ACS Publications
Quantum coherence is detected in the 4f single-ion magnet (SIM) Yb (trensal), by isotope
selective pulsed EPR spectroscopy on an oriented single crystal. At X-band, the spin–lattice …

Lanthanide single molecule magnets: progress and perspective

P Zhang, L Zhang, J Tang - Dalton Transactions, 2015 - pubs.rsc.org
The last few years have seen a huge renaissance in the study of single molecule magnets
(SMMs) thanks to the extensive applications of lanthanide ions with large inherent …