Design, synthesis and physico-chemical studies of a Co (II)/Co (III) mixed-valence complex: An experimental and DFT approach

I Hamdi, N Mhadhbi, N Issaoui, A Roodt… - Journal of Molecular …, 2021 - Elsevier
Abstract The bidentate amine, 2-picolylamine [2-(aminomethyl) pyridine: AMP], and
concentrated hydrobromic acid have been used to synthesize a Co II/Co III mixed-valence …

A mononuclear Co (II) complex: Crystal structure, thermal behavior, optical properties and biological activities

S Dgachi, F Rahmouni, A Soran, M Saoudi… - Journal of Molecular …, 2021 - Elsevier
A new mononuclear cobalt hybrid material (C 6 H 9 N 2) 2 [CoCl 4] was prepared using slow
evaporation technique at room temperature. The X-ray diffraction analysis revealed that the …

A new supramolecular semi conductor cobalt organometallic complex: Structural study, optical and electrical properties

BENN Ameni, O Abderrazek, R Thierry… - Journal of Molecular …, 2022 - Elsevier
Crystals of a novel Cobalt complex [Co (C 3 H 7 NO) 6][CoBr 1.93 Cl 2.07] were synthesized
by a slow evaporation technique at room temperature. Crystal structure, energy dispersive X …

A New Hybrid Organic–Inorganic Salt: bis(3-Aminopyridinium)Tetrachlorocobaltate(II), Application in the Synthesis of Nanostructured Co3O4 for Hexavalent …

I Chérif, S Hassen, I Jendoubi, F Mbarek… - Journal of Cluster …, 2023 - Springer
Single crystals of bis (3-aminopyridinium) tetrachlorocobaltate (II) were successfully
synthesized and structurally characterized using single crystal X-ray diffraction. This study …

Experimental and theoretical investigations on structural-function relationship of new iron (III) complex with 2-(Ammoniomethyl) pyridinium cation as ligand: A …

I Hamdi, N Mhadhbi, N Issaoui, M El-Ghozzi… - Journal of Molecular …, 2022 - Elsevier
Abstract Crystals of (H 2 AMP) 2 [Fe III Br 4] Br 3, where AMP refers to the 2-
(Ammoniomethyl) pyridinium ligand, have been successfully synthesized through redox …

Exploring the white light emission properties and biological activities of a cobalt based mixed halide hybrid material

AB Nasr, S Elleuch, O Majdoub, M Saoudi… - Inorganic Chemistry …, 2025 - Elsevier
In this study, we investigate a novel low-dimensional mixed halide cobalt based hybrid
material with the formula (C 5 H 14 N 2)[CoBr 2.48 Cl 1.52], which intriguingly exhibits both …

Low pH-induced lone-pair activity in the hybrid (C6H10N2)[SnCl3] Cl: Chemical study and physical characterizations

I Sayer, N Dege, H Ghalla, H Naïli - Journal of Molecular Structure, 2022 - Elsevier
By changing the synthesis method and through the pourbaix diagram, a novel 0D organic−
inorganic hybrid like perovskite system was crystallized by slow evaporation in an aqueous …

A novel mixed halide co-based hybrid compound: crystal structure, Hirshfeld surface analysis and thermal behavior

I Kadri, A Ben Nasr, W Rekik - Journal of the Iranian Chemical Society, 2023 - Springer
A great deal of interest has been devoted to the design of a novel cobalt-based hybrid-
material with interesting structure properties. Crystals of (C6H16N) 2 [CoBr2. 06Cl1. 94](1) …

Synthesis, crystal structure, spectroscopic properties, thermal behavior and DFT studies of a new organic-inorganic hybrid [4FBzTPP] 2 [CoBr4]

ZH Zhang, YT Li, MT Zhu, L Huang, ZM Wen… - Journal of Molecular …, 2024 - Elsevier
A new organic-inorganic hybrid [4FBzTPP] 2 [CoBr 4](1)(4FBzTPP= 4-
fluorobenzyltriphenylphosphonium) was synthesized and characterized by X-ray diffraction …

Investigation on structural, thermal, electrical and optical properties of a new (OIH) material based Co (II)

A Tounsi, M Gargouri, AB Salah, B Hamdi - Journal of Molecular Structure, 2023 - Elsevier
At room temperature, a new compound with formula (C 6 H 10 (NH 3) 2) 2 [CoCl 4] Cl 2· H 2
O is successfully synthesized by slow evaporation technique. Then, it is characterized by X …