Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …

Intramolecular vibrational energy transfer is a process central to many physical and
chemical phenomena in molecules. Here, various theories describing the process are …

Photodissociation induced by the absorption of single photons permits the detailed study of
molecular dynamics such as the breaking of bonds, internal energy transfer and …

The second edition of an established graduate text, this book complements the material for a
typical advanced graduate course in quantum mechanics by showing how the underlying …

A brief history is presented, outlining the development of rate theory during the past century.
Starting from Arrhenius [Z. Phys. Chem. 4, 226 (1889)], we follow especially the formulation …

The dynamics of the F+ H2 reaction have been investigated in a high resolution crossed
molecular beam study. Differential cross sections and kinetic energy distributions were …

We develop Wigner's approach to a dynamical transition state theory in phase space in both
the classical and quantum mechanical settings. The key to our development is the …

▪ Abstract Recent studies of state-resolved angular distributions show the participation of
reactive scattering resonances in the simplest chemical reaction. This review is intended for …

A transition state switching model is developed for use in systems where more than one
transition state occurs along the reaction coordinate. The model is cast in the perspective of …

The fundamental assumption of transition state theory is the existence of a dividing surface
having the property that trajectories originating in reactants (resp. products) must cross the …