The design and synthesis of transition metal complexes with high thermal stability in olefin
polymerization have become more and more important in order to meet the need of …

The chemistry of redox-active bis (imino) acenaphthenes (BIAN, R-bian) and metal
complexes based on them has been a rapidly developing field since the 1990s. The key …

ABSTRACT A series of 1‐(2, 6‐dibenzhydryl‐4‐fluorophenylimino)‐2‐
aryliminoacenaphthylene derivatives (L1–L5) and their halonickel complexes LNiX2 (X= Br …

A series of 1-(2-benzhydrylnaphthylimino)-2-phenyliminoacenaphthylene derivatives (L1–
L5) was synthesized, characterized, and then reacted with (DME) NiBr2 to form the …

Naphthyl-a-diimine nickel complexes with systematically varied ligand sterics, activated by
modified methylaluminoxane (MMAO), were tested in the polymerization of higher a-olefin (1 …

The chain-walking polymerization of linear internal alkenes (ie, trans-2-, 3-, and 4-octenes)
using α-diimine nickel catalysts activated with modified methylaluminoxane (MMAO) was …

A series of α‐diimine nickel (II) catalysts bearing different para‐substituted groups,{[(4‐R‐2,
6‐Me2‐C6H2N C) 2Nap] NiBr2, Nap: 1, 8‐naphthdiyl; R= CHMePh (C1); R= CHPh2 (C2); …

A series of 1-[2, 4-bis (bis (4-fluorophenyl) methyl) naphthylimino]-2-
aryliminoacenaphthylene derivatives (L1–L5) was prepared and used to react with (DME) …

A series of α-diimine Ni (II) complexes containing bulky phenyl groups,[ArN= C (Naphth) C=
NAr] NiBr2 (Naphth: 1, 8-naphthdiyl, Ar= 2, 6-Me2-4-PhC6H2 (C1); Ar= 2, 4-Me2-6-PhC6H2 …

A series of para‐phenyl‐substituted α‐diimine nickel complexes,[(2, 6‐R2‐4‐PhC6H2N═ C
(Me)) 2] NiBr2 (R= i Pr (1); R= Et (2); R= Me (3); R= H (4)), were synthesized and …