Soft chemistry of ion-exchangeable layered metal oxides

R Uppuluri, AS Gupta, AS Rosas… - Chemical Society …, 2018 - pubs.rsc.org
Soft chemical reactions such as ion-exchange and acid–base reactions have been
extensively investigated to synthesize novel metastable layered inorganic solids, to exfoliate …

Hybrid improper ferroelectricity: a theoretical, computational, and synthetic perspective

NA Benedek, MA Hayward - Annual Review of Materials …, 2022 - annualreviews.org
We review the theoretical, computational, and synthetic literature on hybrid improper
ferroelectricity in layered perovskite oxides. Different ferroelectric mechanisms are described …

Electron microscopy study of delamination in dispersions of the perovskite-related layered phases K [Ca2Nan-3NbnO3n-1]: evidence for single-layer formation

MMJ Treacy, SB Rice, AJ Jacobson… - Chemistry of …, 1990 - ACS Publications
Intercalation of basic surfactant molecules into the layered perovskites H [Ca2Na
„_3Nbn03n+ 1], n= 3-5, can be used to cause spontaneous exfoliation of the structure into …

Boosting selective Cs+ uptake through the modulation of stacking modes in layered niobate-based perovskites

HY Sun, ZH Chen, B Hu, JH Tang, L Yang… - Nature …, 2024 - nature.com
Selective separation of 137Cs is significant for the sustainable development of nuclear
energy and environmental protection, due to its strong radioactivity and long half-life …

A2Ln2Ti3O10 (A= potassium or rubidium; Ln= lanthanum or rare earth): a new series of layered perovskites exhibiting ion exchange

J Gopalakrishnan, V Bhat - Inorganic Chemistry, 1987 - ACS Publications
H2La2TÍ3O10 3.820 (9) 27.66 (7) H2Sm2Ti3O10 3.780 (13) 26.75 (9) H2Gd2Ti3O10 3.768
(7) 26.61 (5) H2Dy2Ti30! o 3.755 (7) 26.48 (5) compensate for the loss due to volatilization …

Photoluminescence of Perovskite Nanosheets Prepared by Exfoliation of Layered Oxides, K2Ln2Ti3O10, KLnNb2O7, and RbLnTa2O7 (Ln: Lanthanide Ion)

S Ida, C Ogata, M Eguchi, WJ Youngblood… - Journal of the …, 2008 - ACS Publications
Luminescent perovskite nanosheets were prepared by exfoliation of single-or double-
layered perovskite oxides, K2Ln2Ti3O10, KLnNb2O7, and RbLnTa2O7 (Ln: lanthanide ion) …

Progress toward solid state synthesis by design

JR Chamorro, TM McQueen - Accounts of chemical research, 2018 - ACS Publications
Conspectus Ages of history are defined by the underlying materials that promoted human
development: stone, bronze, and iron ages. Since the middle of the last century, humanity …

A novel series of photocatalysts with an ion-exchangeable layered structure of niobate

K Domen, J Yoshimura, T Sekine, A Tanaka, T Onishi - Catalysis letters, 1990 - Springer
Ion-exchangeable niobates, A (M n− 1 Nb n O 3 n+ 1)(A= Na, K, Rb, Cs; M= La, Ca etc.), with
a layered perovskite structure are found to show a unique photocatalytic activity, especially …

Visible light-induced photocatalytic behavior of a layered perovskite-type rubidium lead niobate, RbPb2Nb3O10

J Yoshimura, Y Ebina, J Kondo, K Domen… - The Journal of …, 1993 - ACS Publications
Photocatalytic behaviors of some modified layered compounds derived from RbPb2Nb3Oio
which was an ion exchanger with perovskite structure were examined. Under visible light …

Synthesis, structural, magnetic and transport properties of layered perovskite-related titanates, niobates and tantalates of the type AnBnO3n+ 2, A′ Ak− 1BkO3k+ 1 …

F Lichtenberg, A Herrnberger… - Progress in Solid State …, 2008 - Elsevier
This article represents a continuation of a paper on AnBnO3n+ 2= ABOx compounds which
was published in 2001 in this journal. This work reports also on oxides of the type A′ Ak …