Towards chemistry at absolute zero

BR Heazlewood, TP Softley - Nature Reviews Chemistry, 2021 - nature.com
The prospect of cooling matter down to temperatures that are close to absolute zero raises
intriguing questions about how chemical reactivity changes under these extreme conditions …

Density functional theory: Foundations reviewed

ES Kryachko, EV Ludena - Physics Reports, 2014 - Elsevier
Guided by the above motto (quotation), we review a broad range of issues lying at the
foundations of Density Functional Theory, DFT, a theory which is currently omnipresent in …

A stable compound of helium and sodium at high pressure

X Dong, AR Oganov, AF Goncharov, E Stavrou… - Nature Chemistry, 2017 - nature.com
Helium is generally understood to be chemically inert and this is due to its extremely stable
closed-shell electronic configuration, zero electron affinity and an unsurpassed ionization …

Cold and controlled chemical reaction dynamics

J Toscano, HJ Lewandowski… - Physical Chemistry …, 2020 - pubs.rsc.org
The prospect of studying state-to-state chemical reaction dynamics, with full control over all
of the reaction parameters, is becoming a reality for a small number of systems. Thanks to …

Quantum ergodicity and energy flow in molecules

DM Leitner - Advances in Physics, 2015 - Taylor & Francis
We review a theory for coupled many-nonlinear oscillator systems that describes quantum
ergodicity and energy flow in molecules. The theory exploits the isomorphism between …

Three-body recombination in physical chemistry

M Mirahmadi, J Pérez-Ríos - International Reviews in Physical …, 2022 - Taylor & Francis
Three-body recombination, or ternary association, is a termolecular reaction in which three
particles collide, forming a bound state between two, whereas the third escapes freely …

Elastic and glancing-angle rate coefficients for heating of ultracold Li and Rb atoms by collisions with room-temperature noble gases, H2, and N2

J Kłos, E Tiesinga - The Journal of Chemical Physics, 2023 - pubs.aip.org
Trapped ultracold alkali-metal atoms can be used to measure pressure in the ultra-high-
vacuum and XHV pressure regimes, those with p< 10− 6 Pa. This application for ultracold …

Alignment and Imaging of the Dimer Inside Helium Nanodroplets

JD Pickering, B Shepperson, BAK Hübschmann… - Physical review …, 2018 - APS
The carbon disulphide (CS 2) dimer is formed inside He nanodroplets and identified using fs
laser-induced Coulomb explosion, by observing the CS 2+ ion recoil velocity. It is then …

Molecular collisions: From near-cold to ultra-cold

Y Liu, L Luo - Frontiers of Physics, 2021 - Springer
In the past two decades, the revolutionary technologies of creating cold and ultracold
molecules have provided cutting-edge experiments for studying the fundamental …

Ion-atom-atom three-body recombination: From the cold to the thermal regime

M Mirahmadi, J Pérez-Ríos - The Journal of Chemical Physics, 2023 - pubs.aip.org
We present a study on ion–atom–atom reaction A+ A+ B+ in a wide range of systems and
collision energies ranging from 100 μK to 10 5 K, analyzing two possible products …