Intrinsic Mitochondrial Reactive Oxygen Species (ROS) Activate the In Situ Synthesis of Trimethine Cyanines in Cancer Cells

H Heng, G Song, X Cai, J Sun, K Du… - Angewandte …, 2022 - Wiley Online Library
Environment‐responsive in situ synthesis of molecular fluorescent dyes is challenging.
Herein, we develop a photoextension strategy to make trimethine cyanines with decent …

Iodine oxidation by hydrogen peroxide in acidic solutions, Bray-Liebhafsky reaction and other related reactions

G Schmitz - Physical Chemistry Chemical Physics, 2010 - pubs.rsc.org
The kinetics of the iodine oxidation by hydrogen peroxide is a complicated function of the
concentrations of iodine, hydrogen peroxide, perchloric acid and iodate. A proposed model …

Kinetics of the iodate reduction by hydrogen peroxide and relation with the Briggs–Rauscher and Bray–Liebhafsky oscillating reactions

G Schmitz, S Furrow - Physical Chemistry Chemical Physics, 2012 - pubs.rsc.org
The iodate reduction by hydrogen peroxide in acidic solutions is part of the Bray–Liebhafsky
and Briggs–Rauscher oscillating reactions. At low hydrogen peroxide concentrations, typical …

A modified recipe and variations for the Briggs–Rauscher oscillating reaction

SD Furrow - Journal of Chemical Education, 2012 - ACS Publications
A modified recipe for the Briggs–Rauscher oscillating reaction is suggested. The modified
recipe,[H2SO4]= 0.10 M,[KIO3]= 0.020 M,[NaIO4]= 0.00062 M,[malonic acid]= 0.050 …

Regularity of Intermittent Bursts in BriggsRauscher Oscillating Systems with Phenol

ŽD Čupić, LZ Kolar‐Anić, SR Anić… - Helvetica Chimica …, 2014 - Wiley Online Library
The intermittency or intermittent bursting as the type of dynamic state when two qualitatively
different behaviors replace one another randomly during the course of the reaction, although …

Effects of Ce (III) and Mn (II) on the Dushman reaction and simulations of the Briggs–Rausher reaction

G Schmitz, G Bourceanu, I Ungureanu - Reaction Kinetics, Mechanisms …, 2018 - Springer
The Dushman reaction (reduction of iodate by iodide) is a subsystem of the Briggs–Rausher
oscillating reaction. We show that the previously observed effects of Ce (III) and Mn (II) on …

Reaction Routes Leading to CO2 and CO in the Briggs−Rauscher Oscillator: Analogies between the Oscillatory BR and BZ Reactions

N Muntean, G Szabó, M Wittmann… - The Journal of …, 2009 - ACS Publications
With Fenton-type experiments, it is shown that the intense CO2/CO evolution in the Briggs−
Rauscher (BR) reaction is due to decarboxylation/decarbonylation of organic free radicals …

Study of the transition to higher iodide in the malonic acid Briggs–Rauscher oscillator

SD Furrow, R Cervellati, E Greco - Reaction Kinetics, Mechanisms and …, 2016 - Springer
The interesting behavior of the Briggs–Raucher oscillating reaction does not stop with the
end of oscillations. Depending on the initial concentrations, the classic mixture with malonic …

Iodomalonic Acid as an Anti-Inhibitor in the Resorcinol Inhibited Briggs− Rauscher Reaction

T Lawson, J Fülöp, M Wittmann… - The Journal of …, 2009 - ACS Publications
It was found that the inhibitory effect of resorcinol is less pronounced if it is added in a later
stage of the Briggs− Rauscher reaction, which indicates that an accumulating intermediate …

Reactions of iodate with iodine in concentrated sulfuric acid. Formation of I (+ 3) and I (+ 1) compounds

G Schmitz, Z Noszticzius, G Hollo, M Wittmann… - Chemical Physics …, 2018 - Elsevier
The absorption spectra in a large range of concentrations show that the reactions of iodate
with iodine in 96% sulfuric acid produce (IO) HSO 4, I 3+ and I 5+, just like in the pure 100 …