Review on the accelerated and low-temperature polymerization of benzoxazine resins: addition polymerizable sustainable polymers

B Lochab, M Monisha, N Amarnath, P Sharma… - Polymers, 2021 - mdpi.com
Due to their outstanding and versatile properties, polybenzoxazines have quickly occupied a
great niche of applications. Developing the ability to polymerize benzoxazine resin at lower …

Overview and historical background of polybenzoxazine research

H Ishida - Handbook of benzoxazine resins, 2011 - Elsevier
Publisher Summary This chapter points out that naming of polybenzoxazine is very complex
due to the rich variety of structures from similar raw materials available. The general …

Synthesis and characterization of partially fluorinated polybenzoxazine resins utilizing octafluorocyclopentene as a versatile building block

J Wu, Y Xi, GT McCandless, Y Xie, R Menon… - …, 2015 - ACS Publications
Two new fluorinated diamine-based benzoxazines using octafluorocyclopentene (OFCP) as
a building block have been developed. Monomers were synthesized via two distinct …

Thermally curable acetylene-containing main-chain benzoxazine polymers via sonogashira coupling reaction

K Dogan Demir, B Kiskan, Y Yagci - Macromolecules, 2011 - ACS Publications
Propargyl containing thermally curable benzoxazine precursors in the main chain have
been synthesized from iodo functional bisbenzoxazine and diacetylenes by Sonogashira …

Biobased chitosan/polybenzoxazine cross-linked films: preparation in aqueous media and synergistic improvements in thermal and mechanical properties

AA Alhwaige, T Agag, H Ishida… - Biomacromolecules, 2013 - ACS Publications
A novel class of polymer blends has been prepared from main-chain-type benzoxazine
polymer (MCBP) and chitosan (CTS), a modified biomacromolecule. A water-soluble, main …

Phloretic acid as an alternative to the phenolation of aliphatic hydroxyls for the elaboration of polybenzoxazine

A Trejo-Machin, P Verge, L Puchot, R Quintana - Green Chemistry, 2017 - pubs.rsc.org
3-(4-Hydroxyphenyl) propanoic acid, so-called phloretic acid (PA), is a naturally occurring
phenolic compound which can be produced by the hydrogenation of p-coumaric acid or …

Light responsive chemistry–A design strategy for remodelling benzoxazine architectures towards room temperature processing

P Sharma, M Hakkarainen - Materials Today Chemistry, 2024 - Elsevier
Polybenzoxazines, a novel class of phenolic thermosetting polymers, are admired for the
molecular design versatility, high service temperature, appreciable chemical resistance, and …

3D printing of dual-cure benzoxazine networks

JJ Weigand, CI Miller, AP Janisse, OD McNair, K Kim… - Polymer, 2020 - Elsevier
A novel 3D printing formulation based on a multifunctional benzoxazine (BOX) monomer
possessing both photo and thermally polymerizable functional groups is reported. Printing …

Coumarines as masked phenols for amide functional benzoxazines

G Kaya, B Kiskan, Y Yagci - Polymer Chemistry, 2019 - pubs.rsc.org
Benzoxazines with amide linkages were successfully prepared. Initially, 3, 4-
dihydrocoumarine (DHC) was used as the reagent to synthesize phenolic amides via a ring …

Synthesis of polybenzoxazine precursors using thiols: Simultaneous thiol–ene and ring‐opening reactions

Z Beyazkilic, MU Kahveci, B Aydogan… - Journal of Polymer …, 2012 - Wiley Online Library
A new class of polybenzoxazine precursors of combined molecular structure of benzoxazine
in the open and ring form has been developed. Thermally curable benzoxazine networks …