Oxidative two-state photoreactivity of a manganese (IV) complex using near-infrared light

NR East, R Naumann, C Förster, C Ramanan… - Nature Chemistry, 2024 - nature.com
Highly reducing or oxidizing photocatalysts are a fundamental challenge in photochemistry.
Only a few transition metal complexes with Earth-abundant metal ions have so far advanced …

Spectroelectrochemistry as a powerful technique for porphyrins/corroles derivatives electro-characterization: fundamentals and some examples

B Dozza, BM Rodrigues, I Tisoco, VB de Souza… - Microchemical …, 2022 - Elsevier
Porphyrins and corroles are at the same time very similar and distinct species. Porphyrins
are present in nature and are well known by scientists for almost two centuries (1840) …

Saturation effects in nonlinear absorption, refraction, and frequency conversion: A review

AS Rao - Optik, 2022 - Elsevier
Over the past few decades, there has been extensive research work carried out in the area
of nonlinear optics and opened a myriad of applications in material science and …

Photochemical and photophysical dynamics of the aqueous ferrate (VI) ion

C Antolini, CD Spellman Jr, CJ Otolski… - Journal of the …, 2022 - ACS Publications
Ferrate (VI) has the potential to play a key role in future water supplies. Its salts have been
suggested as “green” alternatives to current advanced oxidation and disinfection methods in …

Effects of environment on the photophysical characteristics of mesotetrakis methylpyridiniumyl porphyrin (TMPyP)

PJ Gonçalves, PL Franzen, DS Correa… - … Acta Part A: Molecular …, 2011 - Elsevier
Porphyrins are an important class of organic molecules, with interesting linear and nonlinear
optical properties given mainly by their extended π-conjugation structure. Their …

Effect of interaction with micelles on the excited-state optical properties of zinc porphyrins and J-aggregates formation

PJ Gonçalves, DS Corrêa, PL Franzen… - … Acta Part A: Molecular …, 2013 - Elsevier
This work reports on the photophysical properties of zinc porphyrins meso-tetrakis
methylpyridiniumyl (Zn2+ TMPyP) and meso-tetrakis sulfonatophenyl (Zn2+ TPPS) in …

Photocatalytic Oxygenation of 10-Methyl-9,10-dihydroacridine by O2 with Manganese Porphyrins

J Jung, K Ohkubo, DP Goldberg… - The Journal of Physical …, 2014 - ACS Publications
Photocatalytic oxygenation of 10-methyl-9, 10-dihydroacridine (AcrH2) by dioxygen (O2)
with a manganese porphyrin [(P) MnIII: 5, 10, 15, 20-tetrakis-(2, 4, 6-trimethylphenyl) …

Electron transfer and catalysis with high-valent metal-oxo complexes

S Fukuzumi - Dalton Transactions, 2015 - pubs.rsc.org
High-valent metal-oxo complexes are produced by reductive activation of dioxygen via
reduction of metal complexes with reductants and dioxygen. Photoinduced electron transfer …

Photocatalytic oxygenation of substrates by dioxygen with protonated manganese (III) corrolazine

J Jung, HM Neu, P Leeladee, MA Siegler… - Inorganic …, 2016 - ACS Publications
UV–vis spectral titrations of a manganese (III) corrolazine complex [MnIII (TBP8Cz)] with
HOTf in benzonitrile (PhCN) indicate mono-and diprotonation of MnIII (TBP8Cz) to give MnIII …

Photochemical oxidation of a manganese (III) complex with oxygen and toluene derivatives to form a manganese (V)-oxo complex

J Jung, K Ohkubo, KA Prokop-Prigge, HM Neu… - Inorganic …, 2013 - ACS Publications
Visible light photoirradiation of an oxygen-saturated benzonitrile solution of a manganese
(III) corrolazine complex [(TBP8Cz) MnIII](1):[TBP8Cz= octakis (p-tert-butylphenyl) …