Dynamic molecular crystals with switchable physical properties

O Sato - Nature chemistry, 2016 - nature.com
The development of molecular materials whose physical properties can be controlled by
external stimuli—such as light, electric field, temperature, and pressure—has recently …

Proton-coupled electron transfer

MHV Huynh, TJ Meyer - Chemical Reviews, 2007 - ACS Publications
At the core of many important energy conversion processes in chemistry and biology are
oxidation-reduction reactions in which both electrons and protons are transferred. An …

Proton-coupled electron transfer

RI Cukier, DG Nocera - Annual review of physical chemistry, 1998 - annualreviews.org
▪ Abstract Proton-coupled electron transfer (PCET) is an important mechanism for charge
transfer in a wide variety of systems including biology-and materials-oriented venues. We …

Activation of hydrogen-and halogen-bonding interactions in tetrathiafulvalene-based crystalline molecular conductors

M Fourmigué, P Batail - Chemical reviews, 2004 - ACS Publications
The purpose of this review is to provide a perspective on the effort accomplished to direct
intermolecular interactions in crystalline molecular conductors based on tetrathiafulvalene …

Toward the construction of functional solid-state supramolecular metal complexes containing copper (I) and silver (I)

M Munakata, LP Wu, T Kuroda-Sowa - Advances in Inorganic Chemistry, 1998 - Elsevier
Publisher Summary This chapter discusses construction of functional solid-state
supramolecular metal complexes containing copper (I) and silver (I). The copper (I) and …

Hydrogen-bond-dynamics-based switching of conductivity and magnetism: A phase transition caused by deuterium and electron transfer in a hydrogen-bonded purely …

A Ueda, S Yamada, T Isono, H Kamo… - Journal of the …, 2014 - ACS Publications
A hydrogen bond (H-bond) is one of the most fundamental and important noncovalent
interactions in chemistry, biology, physics, and all other molecular sciences. Especially, the …

Chemical design and physical properties of dynamic molecular assemblies

T Akutagawa - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
The thermally activated motional freedom of protons (H+), ions (M+), and molecules can be
controlled using supramolecular approaches. In single crystals, motional freedom is enabled …

Synthesis, Properties, Crystal Structures, and Semiconductor Characteristics of Naphtho[1,2-b:5,6-b′]dithiophene and -diselenophene Derivatives

S Shinamura, E Miyazaki… - The Journal of Organic …, 2010 - ACS Publications
In this paper we present the synthesis, structures, characterization, and applications to field-
effect transistors (FETs) of naphtho [1, 2-b: 5, 6-b′] dithiophene (NDT) and-diselenophene …

Hydrogen-bond interaction in organic conductors: redox activation, molecular recognition, structural regulation, and proton transfer in donor− acceptor charge-transfer …

T Murata, Y Morita, Y Yakiyama, K Fukui… - Journal of the …, 2007 - ACS Publications
Hydrogen-bond interaction in donor− acceptor charge-transfer complexes of TTF-imidazole
demonstrated the electronic effects in terms of control of component ratio and redox …

Cation-driven electron transfer involving a spin transition at room temperature in a cobalt iron cyanide thin film

O Sato, Y Einaga, T Iyoda, A Fujishima… - The Journal of …, 1997 - ACS Publications
The electronic structure of a cobalt iron cyanide thin film, Na0. 4Co1. 3 [Fe (CN) 6] 5H2O,
was switched from FeIII (low spin)− CN− CoII (high spin) to FeII (low spin)− CN− CoIII (low …