Aqueous-phase organometallic catalysis: concepts and applications

B Cornils, WA Herrmann - 2004 - books.google.com
Now in its second completely revised and expanded edition. Written by the renowned
editors B. Cornils and WA Herrmann, this book presents every important aspect of aqueous …

Hydrophilic ligands and their application in aqueous-phase metal-catalyzed reactions

KH Shaughnessy - Chemical reviews, 2009 - ACS Publications
Water is truly ubiquitous. Approximately 80% of the earth's surface is covered by water,
although only 1% of this is drinkable water. Water is the solvent of life and makes up about …

Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media

S Moret, PJ Dyson, G Laurenczy - Nature communications, 2014 - nature.com
The chemical transformation of carbon dioxide into useful products becomes increasingly
important as CO2 levels in the atmosphere continue to rise as a consequence of human …

Selective hydrogenation of α, β-unsaturated aldehydes

P Gallezot, D Richard - Catalysis Reviews, 1998 - Taylor & Francis
The synthesis of a large number of fine chemicals, particularly in the field of flavor and
fragrance chemistry [1, 2] and pharmaceuticals [3], involves the selective hydrogenation of …

Coordination chemistry of 1, 3, 5-triaza-7-phosphaadamantane (PTA): Transition metal complexes and related catalytic, medicinal and photoluminescent applications

AD Phillips, L Gonsalvi, A Romerosa, F Vizza… - Coordination Chemistry …, 2004 - Elsevier
The cage-like water-soluble monodentate phosphine 1, 3, 5-triaza-7-phosphaadamantane
(PTA) has received renewed interest in the recent literature due to its properties to solubilize …

Homogeneous catalysts based on water-soluble phosphines

N Pinault, DW Bruce - Coordination chemistry reviews, 2003 - Elsevier
Aryl-and alkyl-substituted tertiary phosphines are among the most common ligands used in
homogeneous catalysts, but they are hydrophobic, as in general are the products of the …

RhIII‐ and IrIII‐Catalyzed Asymmetric Transfer Hydrogenation of Ketones in Water

X Wu, X Li, A Zanotti‐Gerosa, A Pettman… - … A European Journal, 2008 - Wiley Online Library
Asymmetric transfer hydrogenation (ATH) of ketones by formate in neat water is shown to be
viable with Rh‐TsDPEN and Ir‐TsDPEN catalysts, derived in situ from [Cp* MCl2] 2 (M= Rh …

Induced Micellization by Interaction of Poly(2-vinylpyridine)-block-poly(ethylene oxide) with Metal Compounds. Micelle Characteristics and Metal Nanoparticle …

LM Bronstein, SN Sidorov, PM Valetsky, J Hartmann… - Langmuir, 1999 - ACS Publications
Interaction of poly (2-vinylpyridine)− poly (ethylene oxide)(P2VP-b-PEO) diblock copolymers
with noble metal compounds in aqueous media and metal nanoparticle formation in such …

pH-Dependent Transfer Hydrogenation of Water-Soluble Carbonyl Compounds with [Cp*IrIII(H2O)3]2+ (Cp* = η5-C5Me5) as a Catalyst Precursor and …

S Ogo, N Makihara, Y Watanabe - Organometallics, 1999 - ACS Publications
This paper reports a pH-dependent hydrogenation of water-soluble carbonyl compounds by
hydrogen transfer from HCOONa as a hydrogen source (transfer hydrogenation) promoted …

Scope and mechanism of the C− H bond activation reactivity within a supramolecular host by an iridium guest: a stepwise ion pair guest dissociation mechanism

DH Leung, RG Bergman… - Journal of the American …, 2006 - ACS Publications
A chiral self-assembled supramolecular M4L6 assembly has been shown to be a suitable
host for a series of reactive monocationic half-sandwich iridium guests 1, 3, and 4 that are …