Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Opportunities and challenges for combining chemo-and biocatalysis

F Rudroff, MD Mihovilovic, H Gröger, R Snajdrova… - Nature Catalysis, 2018 - nature.com
The past decade has seen a substantial increase in successful examples of the combination
of chemo-and biocatalysis for multistep syntheses. This is driven by obvious advantages …

Construction of chemoenzymatic cascade reactions for bridging chemocatalysis and Biocatalysis: Principles, strategies and prospective

Y Liu, P Liu, S Gao, Z Wang, P Luan… - Chemical Engineering …, 2021 - Elsevier
Multi-step one-pot chemoenzymatic cascade reactions (mo-CECRs) bridging chemo-and
bio-catalysis can not only accomplish chemical transformations with minimized purification …

Amine dehydrogenases: Current status and potential value for chiral amine synthesis

J Liu, W Kong, J Bai, Y Li, L Dong, L Zhou, Y Liu, J Gao… - Chem Catalysis, 2022 - cell.com
Chiral amines are crucial precursors of various pharmaceutical drugs, fine chemicals, and
bioactive molecules. Amine dehydrogenases (AmDHs) have attracted increasing attention …

Enzyme–metal hybrid catalysts for chemoenzymatic reactions

X Li, X Cao, J Xiong, J Ge - Small, 2020 - Wiley Online Library
Enzyme–metal hybrid catalysts (EMHCs), which combine enzymatic and metal catalysis,
provide tremendous possibilities for new chemoenzymatic cascade reactions. Here, an …

Cascade reactions catalyzed by bionanostructures

M Filice, JM Palomo - ACS Catalysis, 2014 - ACS Publications
Cascade reactions are an emerging technology in organic chemistry, introducing elegance
and efficiency to synthetic strategies. This Review provides an overview of the novel and …

Optimisation of catalysts coupling in multi-catalytic hybrid materials: perspectives for the next revolution in catalysis

E Heuson, R Froidevaux, I Itabaiana, R Wojcieszak… - Green …, 2021 - pubs.rsc.org
The search for the optimal coupling of several types of catalysts has inspired the
development of multi-catalytic hybrid materials (MCHMs) featuring chemical and biological …

Synthesis of solid catalysts with spatially resolved acidic and basic molecular functionalities

Z Weng, T Yu, F Zaera - Acs Catalysis, 2018 - ACS Publications
A synthetic procedure was developed to prepare dual acid–base catalysts on a single
platform. Mesoporous SBA-15 was derivatized using known grafting chemistry via the …

One-pot chemo-and photo-enzymatic linear cascade processes

JM Carceller, KS Arias, MJ Climent, S Iborra… - Chemical Society …, 2024 - pubs.rsc.org
The combination of chemo-and photocatalyses with biocatalysis, which couples the flexible
reactivity of the photo-and chemocatalysts with the highly selective and environmentally …

Co-immobilization of enzymes and chemocatalysts for one-pot chemoenzymatic cascades: Scaffold engineering toward more efficient catalysis

T Chen, Y Lu, X Xiong, Z Xu - Chem Catalysis, 2024 - cell.com
The combination of enzymes and chemocatalysts for one-pot chemoenzymatic cascade
reactions has emerged as a promising field for advancing atom-economic and …