Site-predictable and chemoselective C–H bond functionalization reactions offer synthetically
powerful strategies for the step-economic diversification of both feedstock and fine …

Conspectus Carbon dioxide (CO2) is not only a greenhouse gas and a common waste
product but also an inexpensive, readily available, and renewable carbon resource. It is an …

The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Herein, we report a Ni-catalyzed C (sp2)–H hydroxylation of aryl bromides with N2O as an
oxygen-atom donor. The reaction is enabled by a 1, 4-Ni translocation that results in …

Conspectus Migratory cross-coupling via metal migration is a process of significant
academic and industrial interest. It provides an attractive alternative for the selective …

Herein, we report the direct carboxylation of unactivated secondary alkyl bromides enabled
by the merger of photoredox and nickel catalysis, a previously inaccessible endeavor in the …

Conspectus The ubiquity and importance of carboxylic acids and amides in peptides,
pharmaceuticals, agrochemicals, and synthetic materials has challenged chemists to design …

Reductive carboxylation of organo (pseudo) halides with CO2 is a powerful method to
provide carboxylic acids quickly. Notably, the catalytic reductive carbo‐carboxylation of …

As well known, carbon dioxide (CO 2) is an ideal C1 source in organic synthesis due to its
high abundance, low cost, nontoxicity, and renewability. Significant progress has been …

Catalytic carboxylation of C–H bonds using CO2 is a sustainable and economic strategy to
produce valuable carboxylic acids. However, this process presents challenges due to the …