The chemistry of heterocyclic compounds has traditionally been and remains a bright area of
chemical science in Russia. This is due to the fact that many heterocycles find the widest …

The main trends in the chemistry of 1, 2-diphosphacyclopentadienes (1, 2-diphospholes)
and their derivatives 1, 2-diphosphacyclopentadienide anions (1, 2-diphospholide anions) …

A straightforward synthesis of P-chiral polycyclic phosphines by an asymmetric Diels–Alder
reaction of 1-alkyl-1, 2-diphospholes and (5R)-(L-menthyloxy)-2 (5H)-furanone (MOxF) is …

Utilizing the W (CO) 5 group as a promoter, we have established a straightforward pathway
for the conversion of simple 1-alkyl-1, 2-diphospholes to P, P-bidentate caged phosphines …

A one-step diastereoselective synthesis of bulky P-chiral phosphines with a rigid bicyclic
[2.2. 1] structure was developed employing a cycloaddition reaction of 3, 4, 5-triphenyl-1-(+) …

This chapter covers the literature published during 2014 relating to the above area. The
number of papers published in 2014 is similar to that in 2013 and again it has been …

Two different approaches have been employed to enhance the reactivity of 1-alkyl-1, 2-
diphospholes–the introduction of electron-withdrawing groups either at the phosphorus …

Abstract The [4π+ 2π]-cycloaddition of N-phenylmaleimide to 2-tropylcyclohexanone was
performed to prepare previously unknown 9-(2-oxocyclohexyl)-4-phenyl-4-azatetra-cyclo …

Abstract 3, 4, 5‐Triphenyl‐1‐(+)‐neomenthyl‐1, 2‐diphosphole was obtained by alkylation
of sodium 3, 4, 5‐triphenyl‐1, 2‐diphosphacyclopentadienide with (–)‐menthyl tosylate …

Quantum chemical calculations and a comparative analysis of Raman spectra of 3, 4, 5-
triphenyl-1-propyl-1, 2-diphosphole (1), anti-endo-4, 7, 8, 9-tetraphenyl-10-propyl-4-aza-1 …