Siloxane polymers are an important industrial commodity based on the structure–(R2–Si–O)–
. Scission of the siloxane bond is essential, as it is the first step leading to polymerization or …

A novel functional oligomer (Si-TFVE) with a siloxane backbone and thermally cross-
linkable trifluorovinyl ether groups (− OCF CF2) is reported here. When postpolymerized at …

A novel organosiloxane containing a thermally cross-linkable benzocyclobutene group was
successfully synthesized through a one-pot Grignard reaction procedure. The …

Two novel low dielectric polysiloxanes with high thermostability and low water uptake were
developed. These polymers were formed via a thermo-crosslinking reaction of two BCB …

Vinyl silicone oil containing perfluorocyclobutyl aryl ether in the backbone (PFCB–VSO) was
prepared by polycondensation of silane monomer containing perfluorocyclobutyl aryl ether …

Condensation of alkoxysilanes in the active medium, which means acetic or trifluoroacetic
acids, is a convenient and versatile method for preparing silsesquioxane copolymers with …

Polycondensation of diethoxydimethylsilane (DEDMS) in an active medium containing an
excess of acetic acid was studied. It has been shown that the process selectivity could be …

Hydrolytic oxidation of various hydrosilanes in acetonitrile and in the absence of organic
solvents catalyzed by an N-heterocyclic carbene organocatalysis is described. The NHC …

Eugenol-containing oligoorganosilsesquioxanes were synthesized by the method of
hydrolytic polycondensation in an active medium under various reaction conditions. The …

This article discusses the synthesis of polyorganosiloxanes with 1, 1, 1, 2, 2, 3, 3-heptafluoro-
4, 4-bis (trifluoromethyl) pentyl (R f= CF 3 CF 2 CF 2 C (CF 3) 2 (CH 2) 3-) perfluoroalkyl …