Crystal engineering strategies towards halogen-bonded metal–organic multi-component solids: Salts, cocrystals and salt cocrystals

V Nemec, K Lisac, N Bedeković, L Fotović… - …, 2021 - pubs.rsc.org
Over the past several decades, halogen bonding has become a standard 'tool'in
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …

Halogen-bonded cocrystals as optical materials: Next-generation control over light–matter interactions

JC Christopherson, F Topić, CJ Barrett… - Crystal Growth & …, 2018 - ACS Publications
This review summarizes the recent advances in utilizing halogen bond-driven cocrystal
formation as a design element in the creation of optical or photoresponsive materials …

Supramolecular gold stripping from activated carbon using α-cyclodextrin

W Liu, LO Jones, H Wu, CL Stern… - Journal of the …, 2020 - ACS Publications
We report the molecular recognition of the Au (CN) 2–anion, a crucial intermediate in today's
gold mining industry, by α-cyclodextrin. Three X-ray single-crystal superstructures—KAu …

A large family of halogen-bonded cocrystals involving metal–organic building blocks with open coordination sites

V Nemec, L Fotovic, T Friscic, D Cincic - Crystal growth & design, 2017 - ACS Publications
We demonstrate a design for halogen-bonded metal–organic cocrystals involving
coordinatively unsaturated square-planar Cu (II) and Ni (II) centers, by utilizing a Schiff base …

Modulation of metallophilic and π–π interactions in platinum cyclometalated luminophores with halogen bonding

V Sivchik, A Kochetov, T Eskelinen… - … A European Journal, 2021 - Wiley Online Library
Luminescent cyclometalated complexes [M (C^ N^ N) CN](M= Pt, Pd; HC^ N^ N= pyridinyl‐
(M= Pt 1, Pd 5), benzyltriazolyl‐(M= Pt 2), indazolyl‐(M= Pt 3, Pd 6), pyrazolyl …

Improvement of the Photophysical Performance of Platinum‐Cyclometalated Complexes in Halogen‐Bonded Adducts

V Sivchik, RK Sarker, ZY Liu, KY Chung… - … A European Journal, 2018 - Wiley Online Library
Three groups of luminescent platinum complexes [Pt (C^ N)(L)(Y)][C^ N= benzothienyl‐
pyridine (1), bezofuryl‐pyridine (2), phenyl‐pyridine (3); L/Y= DMSO/Cl (a), PPh3/Cl (b) …

Unusual chalcogen⋯ chalcogen interactions in like⋯ like and unlike Y [double bond, length as m-dash] C [double bond, length as m-dash] Y⋯ Y [double bond, length …

MAA Ibrahim, MNI Shehata, MES Soliman… - Physical Chemistry …, 2022 - pubs.rsc.org
Chalcogen⋯ chalcogen interactions were investigated within four types of like⋯ like and
unlike YCY⋯ YCY complexes (where Y= O, S, or Se). A plethora of quantum mechanical …

Dichroic Palladium Dithiolate Coordination Polymers

AS Sergeenko, D Paripovic… - Crystal Growth & …, 2023 - ACS Publications
An isomorphous series of coordination polymers with the general formula M (H2O) 4 [Pd (iso-
maleonitriledithiolate) 2]· 2H2O (M= Mn, Co, Zn) was structurally characterized. They exhibit …

Playing with Isomerism: Cocrystallization of Isomeric N-Salicylideneaminopyridines with Perfluorinated Compounds as Halogen Bond Donors and Its Impact on …

A Carletta, M Zbačnik, M Van Gysel… - Crystal growth & …, 2018 - ACS Publications
In N-salicylideneaniline derivatives, photochromism occurs by a two-step isomerization
mechanism. Photochromism has been reported to be closely related to the molecular …

NaBa 12 (BO 3) 7 F 4 (NBBF) dichroic crystals: optical properties and dielectric permittivity

TB Bekker, AG Khamoyan, AV Davydov… - Dalton …, 2024 - pubs.rsc.org
Three NaBa12 (BO3) 7F4 crystals were grown in the BaO–BaF2–B2O3–Na2O system from
three different compositions of high-temperature solution. With the use of optical …