Advances in one-pot synthesis through borrowing hydrogen catalysis

A Corma, J Navas, MJ Sabater - Chemical reviews, 2018 - ACS Publications
The borrowing hydrogen (BH) principle, also called hydrogen auto-transfer, is a powerful
approach which combines transfer hydrogenation (avoiding the direct use of molecular …

Quinone‐catalyzed selective oxidation of organic molecules

AE Wendlandt, SS Stahl - Angewandte Chemie International …, 2015 - Wiley Online Library
Quinones are common stoichiometric reagents in organic chemistry. Para‐quinones with
high reduction potentials, such as DDQ and chloranil, are widely used and typically promote …

Oxidative cleavage of C–C bonds in lignin

E Subbotina, T Rukkijakan, MD Marquez-Medina… - Nature Chemistry, 2021 - nature.com
Lignin is an aromatic polymer that constitutes up to 30 wt% of woody biomass and is
considered the largest source of renewable aromatics. Valorization of the lignin stream is …

Recent advances in aerobic oxidation of alcohols and amines to imines

B Chen, L Wang, S Gao - ACS catalysis, 2015 - ACS Publications
Imines as valuable intermediates are widely applied in pharmaceutical syntheses and
organic transformation. However, the traditional imine synthesis involves unstable …

CO2-Promoted Reactions: An Emerging Concept for the Synthesis of Fine Chemicals and Pharmaceuticals

PK Sahoo, Y Zhang, S Das - ACS Catalysis, 2021 - ACS Publications
Carbon dioxide is a nontoxic and abundant chemical and has been widely used as a C1
building block for the synthesis of highly important chemicals. This greenhouse gas also has …

Visible-light-assisted aerobic photocatalytic oxidation of amines to imines over NH2-MIL-125 (Ti)

D Sun, L Ye, Z Li - Applied Catalysis B: Environmental, 2015 - Elsevier
Abstract NH 2-MIL-125 (Ti), an amine-functionalized metal-organic-framework (MOF), was
found for the first time to exhibit photocatalytic activity for the aerobic selective oxidation of …

Aerobic oxidative coupling of amines by carbon nitride photocatalysis with visible light

F Su, SC Mathew, L Möhlmann, M Antonietti… - Angewandte …, 2011 - infona.pl
Ein echter Sonnenschein: Eine einfache und effiziente Synthese von Benzoxazolen,
Benzimidazolen und Benzothiazolen gelingt mithilfe eines Eintopfverfahrens, das durch …

Commercial metal–organic frameworks as heterogeneous catalysts

A Dhakshinamoorthy, M Alvaro, H Garcia - Chemical communications, 2012 - pubs.rsc.org
Metal–organic frameworks (MOFs) are porous crystalline materials that have promising
applications as heterogeneous catalysts. After describing the composition, textural …

Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions

JSM Samec, JE Bäckvall, PG Andersson… - Chemical Society …, 2006 - pubs.rsc.org
In this tutorial review recent mechanistic studies on transition metal-catalyzed hydrogen
transfer reactions are discussed. A common feature of these reactions is that they involve …

Catalytic oxidation of organic substrates by molecular oxygen and hydrogen peroxide by multistep electron transfer—a biomimetic approach

J Piera, JE Bäckvall - Angewandte Chemie International …, 2008 - Wiley Online Library
Oxidation reactions are of fundamental importance in nature, and are key transformations in
organic synthesis. The development of new processes that employ transition metals as …