Dynamic relaxations and relaxation-property relationships in metallic glasses

WH Wang - Progress in Materials Science, 2019 - Elsevier
Dynamic relaxation is an intrinsic and universal feature of glasses and enables fluctuation
and dissipation to occur, which induces plentiful behaviour, maintains equilibrium, and …

Physical aging in polymers and polymer nanocomposites: recent results and open questions

D Cangialosi, VM Boucher, A Alegría, J Colmenero - Soft Matter, 2013 - pubs.rsc.org
Physical aging is a ubiquitous phenomenon in glassy materials and originates from the fact
that they are generally out-of-equilibrium. Due to the technological and fundamental …

50th Anniversary Perspective: Challenges in the Dynamics and Kinetics of Glass-Forming Polymers

GB McKenna, SL Simon - Macromolecules, 2017 - ACS Publications
The phenomenology of the glass transition and the associated behavior in the near liquid
and glassy states are detailed, including the cooling rate dependence of the glass transition …

Atomic-Scale Relaxation Dynamics and Aging in a Metallic Glass Probed<? format?> by X-Ray Photon Correlation Spectroscopy

B Ruta, Y Chushkin, G Monaco, L Cipelletti, E Pineda… - Physical review …, 2012 - APS
We use x-ray photon correlation spectroscopy to investigate the structural relaxation process
in a metallic glass on the atomic length scale. We report evidence for a dynamical crossover …

Predicting nonlinear physical aging of glasses from equilibrium relaxation via the material time

B Riechers, LA Roed, S Mehri, TS Ingebrigtsen… - Science …, 2022 - science.org
The noncrystalline glassy state of matter plays a role in virtually all fields of materials science
and offers complementary properties to those of the crystalline counterpart. The caveat of the …

Direct evidence of two equilibration mechanisms in glassy polymers

D Cangialosi, VM Boucher, A Alegría, J Colmenero - Physical review letters, 2013 - APS
We investigated the kinetics of enthalpy recovery of several glass-forming polymers at
temperatures significantly below the glass transition temperature (T g) and for aging times …

Effect of nanostructure on the thermal glass transition and physical aging in polymer materials

D Cangialosi, A Alegria, J Colmenero - Progress in Polymer Science, 2016 - Elsevier
We review the recent activity aiming to clarify glassy dynamics in nanostructured polymer
glasses, in particular thin films, nanocomposites and nanospheres. Special emphasis is …

Dynamics and thermodynamics of polymer glasses

D Cangialosi - Journal of Physics: Condensed Matter, 2014 - iopscience.iop.org
The fate of matter when decreasing the temperature at constant pressure is that of passing
from gas to liquid and, subsequently, from liquid to crystal. However, a class of materials can …

Time reversibility during the ageing of materials

T Böhmer, JP Gabriel, L Costigliola, JN Kociok… - Nature Physics, 2024 - nature.com
Physical ageing is the generic term for irreversible processes in glassy materials resulting
from molecular rearrangements. One formalism for describing such ageing processes …

Revealing the fast atomic motion of network glasses

B Ruta, G Baldi, Y Chushkin, B Rufflé… - Nature …, 2014 - nature.com
Still very little is known on the relaxation dynamics of glasses at the microscopic level due to
the lack of experiments and theories. It is commonly believed that glasses are in a dynamical …