Organometallic chemistry confined within a porphyrin-like framework
The world of modified porphyrins changed forever when an N-confused porphyrin (NCP), a
porphyrin isomer, was first published in 1994. The replacement of one inner nitrogen with a …
porphyrin isomer, was first published in 1994. The replacement of one inner nitrogen with a …
Carbaporphyrinoid systems
TD Lash - Chemical reviews, 2017 - ACS Publications
Following immediately after the serendipitous discovery of N-confused porphyrins,
remarkably diverse carbaporphyrinoid systems have been synthesized and investigated. By …
remarkably diverse carbaporphyrinoid systems have been synthesized and investigated. By …
Out of the blue! Azuliporphyrins and related carbaporphyrinoid systems
TD Lash - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus First reported in 1997, azuliporphyrins have proven to be a truly remarkable
family of porphyrin analogues. In this system, although the porphyrin framework is retained …
family of porphyrin analogues. In this system, although the porphyrin framework is retained …
[HTML][HTML] Organometallic Chemistry within the Structured Environment Provided by the Macrocyclic Cores of Carbaporphyrins and Related Systems
TD Lash - Molecules, 2023 - mdpi.com
The unique environment within the core of carbaporphyrinoid systems provides a platform to
explore unusual organometallic chemistry. The ability of these structures to form stable …
explore unusual organometallic chemistry. The ability of these structures to form stable …
21-Carba-23-oxaporphyrinoids and 21-oxo-21-carba-23-oxaporphyrinoids: macrocyclic π-conjugation involving the carbonyl moiety
A Berlicka, P Foryś-Martowłos, K Hassa… - Organic Chemistry …, 2022 - pubs.rsc.org
A rational synthesis using the carba analogues of tripyrrane and 1, 3-bis (arylhydroxymethyl)
furan as synthons resulted in the formation of 21-carba-23-oxaporphyrin and 21-carba-23 …
furan as synthons resulted in the formation of 21-carba-23-oxaporphyrin and 21-carba-23 …
Palladium (II), ruthenium (II), and ruthenium (III) complexes of 23-thiaazuliporphyrin: the case of coordination-induced contraction
MJ Białek, L Latos-Grażyński - Inorganic Chemistry, 2016 - ACS Publications
5, 10, 15, 20-Tetraaryl-23-thiaazuliporphyrin (SAz) was synthesized starting from
nonfunctionalized azulene using a “1+ 3” method to be applied as a monoanionic …
nonfunctionalized azulene using a “1+ 3” method to be applied as a monoanionic …
Pyreniporphyrins: Porphyrin analogues that incorporate a polycyclic aromatic hydrocarbon subunit within the macrocyclic framework
R Gao, DI AbuSalim, TD Lash - The Journal of Organic Chemistry, 2017 - ACS Publications
The first examples of porphyrin analogues incorporating pyrene units are reported. Acid-
catalyzed condensation of a pyrene dialdehyde with a tripyrrane, followed by oxidation with …
catalyzed condensation of a pyrene dialdehyde with a tripyrrane, followed by oxidation with …
Metalation and Selective Oxidation of Diphenyl-23-oxa-,-thia-, and-selena-21-carbaporphyrins
TD Lash, GM Ferrence - Inorganic Chemistry, 2017 - ACS Publications
The availability of diphenyl-23-oxa-,-thia-, and-selena-21-carbaporphyrins has enabled the
reactivity of these systems to be investigated and contrasted. All three …
reactivity of these systems to be investigated and contrasted. All three …
[HTML][HTML] Color modulation in organometallic dyes. Purple-colored acyclic carbenes derived from 2-isocyanoazulene gold (I) complexes
This study reports new carbene azulene gold (I) complexes [AuCl {C (NHAz)(NR 2)}](R= Me
(1) and n Bu (2)) and [Au (C 6 F 4 OC 10 H 21){C (NHAz)(NR 2)}](R= Me (3) and n Bu (4)) …
(1) and n Bu (2)) and [Au (C 6 F 4 OC 10 H 21){C (NHAz)(NR 2)}](R= Me (3) and n Bu (4)) …
Aromatic Character and Relative Stability of Pyrazoloporphyrin Tautomers and Related Protonated Species: Insights into How Pyrazole Changes the Properties of …
DI AbuSalim, TD Lash - Molecules, 2023 - mdpi.com
Pyrazoloporphyrins (PzPs), which are porphyrin analogues incorporating a pyrazole
subunit, are examples of carbaporphyrin-type structures with a carbon atom within the …
subunit, are examples of carbaporphyrin-type structures with a carbon atom within the …