Inducing magnetic coupling between 4f elements is an ongoing challenge. To overcome this
formidable difficulty, we incorporate highly delocalized tetrazinyl radicals, which strongly …

Abstract Although 1, 2, 4, 5‐tetrazines or s‐tetrazines have been known in the literature for
more than a century, their coordination chemistry has become increasingly popular in recent …

Separation of acetylene (C 2 H 2) from ethylene (C 2 H 4) or carbon dioxide (CO 2) is a vital
and difficult task in petrochemical industry. Owing to the similar physical properties, it is very …

A combination of high-performing lanthanide metallocenes and tetrazine-based radical
ligands leads to a new series of radical-bridged dinuclear lanthanide metallocenes;[(Cp …

The unique electronic nature of the 1, 2, 4, 5-tetrazine or s-tetrazine (tz) ring has sparked
tremendous scientific interest over the last few years. Tetrazines have found numerous …

For the last couple of decades, azabenzene-based ligands have drawn much attention from
inorganic chemists due to their ability to coordinate with different metal ions to form …

The discovery of singular organic radical ligands is a formidable challenge due to high
reactivity arising from the unpaired electron. Matching radical ligands with metal ions to …

Four DyIII complexes,[Dy2 (NO3) 4 (L) 2 (H2O) 2]· 2MeCN (1),[Dy2 (NO3) 4 (L) 2 (H2O) 2]· 2
(NO3)· DMBD· 2MeOH (2),[Dy2 (NO3) 4 (L) 2 (TPO) 2]· 2MeCN (3) and [Dy2 (L′) 6 (H2O) …

Aromatic π-stacking is a weakly attractive, noncovalent interaction often found in biological
macromolecules and synthetic supramolecular chemistry. The weak nondirectional nature of …

Ferromagnetism is rare in pure organic materials. Recently, the perylene diimide radical
anion (PDI−) salt prepared through solvothermal reduction by hydrazine hydrate has shown …