Multifunctionality of luminescent molecular nanomagnets based on lanthanide complexes

R Jankowski, M Wyczesany, S Chorazy - Chemical Communications, 2023 - pubs.rsc.org
Multifunctional materials, which exhibit diverse physical properties, are candidates for the
new generation of smart devices that realize many tasks simultaneously. Particular attention …

[HTML][HTML] Magnetic molecules on surfaces: SMMs and beyond

G Gabarró-Riera, G Aromí, EC Sañudo - Coordination Chemistry Reviews, 2023 - Elsevier
In this critical review we cover the state of the art of surface deposition of complex magnetic
molecules. Deposition methods are reviewed, as well as the most used types of surfaces …

High-temperature magnetic blocking in a monometallic dysprosium azafullerene single-molecule magnet

Z Hu, Y Wang, A Ullah, GM Gutiérrez-Finol… - Chem, 2023 - cell.com
Single-molecule magnets (SMMs) showing magnetic blocking near or above liquid nitrogen
temperature have recently been achieved by inducing exceptionally strong and axial crystal …

Electrophilic trifluoromethylation of dimetallofullerene anions en route to air-stable single-molecule magnets with high blocking temperature of magnetization

Y Wang, G Velkos, NJ Israel… - Journal of the …, 2021 - ACS Publications
Lanthanide dimetallofullerenes with single-electron M–M bonds are an important class of
single molecular magnets and qubit candidates, but stabilization of their unique electronic …

Endohedral metallofullerene molecular nanomagnets

Z Hu, S Yang - Chemical Society Reviews, 2024 - pubs.rsc.org
Magnetic lanthanide (Ln) metal complexes exhibiting magnetic bistability can behave as
molecular nanomagnets, also known as single-molecule magnets (SMMs), suitable for …

Theoretical Insights into the Adsorption of Rare-Earth-Containing Single-Molecule Magnets on Solid Surfaces

JC Ren, J Zhou, S Li, W Liu - The Journal of Physical Chemistry C, 2023 - ACS Publications
Single-molecule magnets (SMMs) offer stable quantum objects capable of exhibiting diverse
magnetic states on the nanoscale, making them promising candidates for storing and …

Nd─Nd Bond in Ih and D5h Cage Isomers of Nd2@C80 Stabilized by Electrophilic CF3 Addition

W Yang, G Velkos, M Rosenkranz… - Advanced …, 2024 - Wiley Online Library
Synthesis of molecular compounds with metal–metal bonds between 4f elements is
recognized as one of the fascinating milestones in lanthanide metallochemistry. The main …

Singly and triply linked magnetic porphyrin lanthanide arrays

JM Van Raden, DI Alexandropoulos… - Journal of the …, 2022 - ACS Publications
The introduction of paramagnetic metal centers into a conjugated π-system is a promising
approach toward engineering spintronic materials. Here, we report an investigation of two …

Characterisation of magnetic relaxation on extremely long timescales

WJA Blackmore, GK Gransbury, P Evans… - Physical Chemistry …, 2023 - pubs.rsc.org
The use of magnetisation decay measurements to characterise very slow relaxation of the
magnetisation in single-molecule magnets is becoming increasingly prevalent as relaxation …

Tailored Lewis acid sites for high-temperature supported single-molecule magnetism

M Bernhardt, MD Korzyński, ZJ Berkson… - Journal of the …, 2023 - ACS Publications
Generating or even retaining slow magnetic relaxation in surface immobilized single-
molecule magnets (SMMs) from promising molecular precursors remains a great challenge …