Advances in the synthesis of preceramic polymers for the formation of silicon-based and ultrahigh-temperature non-oxide ceramics

BJ Ackley, KL Martin, TS Key, CM Clarkson… - Chemical …, 2023 - ACS Publications
Preceramic polymers (PCPs) are a group of specialty macromolecules that serve as
precursors for generating inorganics, including ceramic carbides, nitrides, and borides …

Ceramics and nanostructures from molecular precursors

RJP Corriu - Angewandte Chemie International Edition, 2000 - Wiley Online Library
The elaboration of solids from the molecular scale by a kinetically controlled methodology is
one of the main challenges of molecular chemistry. In the long term, this should permit the …

Comprehensive chemistry of polycarbosilanes, polysilazanes, and polycarbosilazanes as precursors of ceramics

M Birot, JP Pillot, J Dunogues - Chemical reviews, 1995 - ACS Publications
Among the high-performance non-oxide ceramics, silicon carbide (SiC) and nitride (Si3N4)
offer unique potentialities as thermomechanical materials due to their stiffness and …

Preceramic polymer routes to silicon carbide

RM Laine, F Babonneau - Chemistry of materials, 1993 - ACS Publications
Silicon carbide ceramic fibers derived from organometallic polymer precursors offer
exceptional opportunities for the development of high-temperature ceramic and metal matrix …

Synthesis of fluorinated polymers by chemical modification

JJ Reisinger, MA Hillmyer - Progress in polymer science, 2002 - Elsevier
Polymers that contain atomic fluorine in or along the backbone possess many desirable
physical properties. In general, fluoropolymers exhibit high thermal stability, enhanced …

Synthesis and structure of a highly branched polycarbosilane derived from (chloromethyl) trichlorosilane

CK Whitmarsh, LV Interrante - Organometallics, 1991 - ACS Publications
Conclusion Alkylation of glycolate-0, 0derivatives of metal oxides is a better, more direct
wayto organometal oxides, espe-cially when the metal is in the correct oxidation state …

The polymerization behavior of [1]-and [2] ferrocenophanes containing silicon atoms in the bridge: comparison of the molecular structure of the strained, polymerizable …

W Finckh, BZ Tang, DA Foucher, DB Zamble… - …, 1993 - ACS Publications
Ring-opening polymerization is a well-established route to organic polymers and an
increasingly successful method for the synthesis of polymers with main chains comprising …

Poly (methylsilane)—a high ceramic yield precursor to silicon carbide

ZF Zhang, F Babonneau, RM Laine… - Journal of the …, 1991 - Wiley Online Library
Preceramic polymers offer exceptional potential for low‐temperature processing of both
oxide and non‐oxide ceramics. In addition, shapes such as fibers, films, and membranes …

Synthesis, characterization, and properties of high molecular weight unsymmetrically substituted poly (ferrocenylsilanes)

D Foucher, R Ziembinski, R Petersen, J Pudelski… - …, 1994 - ACS Publications
Synthesis, Characterization, and Properties of High Molecular Weight Unsymmetrically
Substituted Poly(ferrocenylsilanes) Page 1 3992 Macromolecules 1994, 27, 3992-3999 …

Silicon carbide—a survey of synthetic approaches, properties and applications

M Jansen, G Roewer, U Herzog, K Trommer… - High performance non …, 2002 - Springer
The challenge to develop tailor-made precursor molecules for silicon carbide has
significantly intensified the progress in synthesis of organosilicon polymers. A critical …