Oxide–and silicate–water interfaces and their roles in technology and the environment

JL Bañuelos, E Borguet, GE Brown Jr… - Chemical …, 2023 - ACS Publications
Interfacial reactions drive all elemental cycling on Earth and play pivotal roles in human
activities such as agriculture, water purification, energy production and storage …

Measuring surface charge: Why experimental characterization and molecular modeling should be coupled

R Hartkamp, AL Biance, L Fu, JF Dufrêche… - Current opinion in …, 2018 - Elsevier
Surface charge controls many static and dynamic properties of soft matter and
micro/nanofluidic systems, but its unambiguous measurement forms a challenge. Standard …

Ion correlations drive charge overscreening and heterogeneous nucleation at solid–aqueous electrolyte interfaces

SS Lee, A Koishi, IC Bourg… - Proceedings of the …, 2021 - National Acad Sciences
Classical electrical double layer (EDL) models are foundational to the representation of
atomistic structure and reactivity at charged interfaces. An important limitation to these …

Surface diffusion enhanced ion transport through two-dimensional nanochannels

Y Jiang, R Hu, C Yang, Z Zhou, G Yuan, H Zhou… - Science …, 2023 - science.org
Fast ion permeation in nanofluidic channels has been intensively investigated in the past
few decades because of their potential uses in separation technologies and osmotic energy …

Stern layer structure and energetics at mica–water interfaces

IC Bourg, SS Lee, P Fenter… - The Journal of Physical …, 2017 - ACS Publications
The screening of surface charge by dissolved ions at solid–liquid interfaces—in the region of
interfacial fluid known as the electrical double layer (EDL)—plays a recurrent role in surface …

Radiocesium interaction with clay minerals: Theory and simulation advances Post–Fukushima

M Okumura, S Kerisit, IC Bourg, LN Lammers… - Journal of …, 2018 - Elsevier
Insights at the microscopic level of the process of radiocesium adsorption and interaction
with clay mineral particles have improved substantially over the past several years, triggered …

Molecular-scale insights into the electrical double layer at oxide-electrolyte interfaces

C Zhang, MF Calegari Andrade, ZK Goldsmith… - Nature …, 2024 - nature.com
The electrical double layer (EDL) at metal oxide-electrolyte interfaces critically affects
fundamental processes in water splitting, batteries, and corrosion. However, limitations in …

Real-time observation of cation exchange kinetics and dynamics at the muscovite-water interface

SS Lee, P Fenter, KL Nagy, NC Sturchio - Nature communications, 2017 - nature.com
Ion exchange at charged solid–liquid interfaces is central to a broad range of chemical and
transport phenomena. Real-time observations of adsorption/desorption at the molecular …

Role of hydration energy and co-ions association on monovalent and divalent cations adsorption at mica-aqueous interface

S Adapa, A Malani - Scientific reports, 2018 - nature.com
Adsorption of ions at the solid-aqueous interface is the primary mechanism in fast biological
processes to very slow geological transformations. Despite, little is known about role of ion …

Studies of Mineral Nucleation and Growth Across Multiple Scales: Review of the Current State of Research Using the Example of Barite (BaSO4)

J Weber, JN Bracco, K Yuan… - ACS Earth and Space …, 2021 - ACS Publications
Sparingly soluble sulfate minerals, particularly barite (BaSO4), present an ideal system to
understand mineral–water interfacial reactions. The model system barite has been used to …