Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

Conspectus The direct transformation of C–H bonds into diverse functional groups
represents one of the most atom-and step-economical strategies for organic synthesis and …

The concurrent installation of C–C and C–N bonds across alkene frameworks represents a
powerful tool to prepare motifs that are ubiquitous in pharmaceuticals and bioactive …

Vicinal diamines are a common structural motif in bioactive natural products, therapeutic
agents, and molecular catalysts, motivating the continuing development of efficient …

The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Given its many distinct characteristics, electrochemistry represents an attractive approach to
meet the prevailing trends in organic synthesis. In particular, electrocatalysis—a process that …

The area of catalysis of radical reactions has recently flourished. Various reaction conditions
have been discovered and explained in terms of catalytic cycles. These cycles rarely stand …

1. INTRODUCTION This review article is concerned with the use of compounds 1 and 2
(Figure 1) as effective and very versatile reagents for trifluoromethylation reactions of a …

Fluorine has emerged as a “magic element” in medicinal chemistry, crop, and materials
science. 1 Although fluorine is the most abundant halogen in the earth's crust, it is contained …

Aliphatic azides are a versatile class of compounds found in a variety of biologically active
pharmaceuticals. These compounds are also recognized as useful precursors for the …